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Merck
CN

695882

PhDave-Phos

97%, powder

别名:

2-二苯基膦-2′-(N,N-二甲基氨基)联苯, 2′-(二苯基膦基)-N,N′-二甲基--(1,1′-联苯)-2-胺, PhDavePhos

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关于此项目

经验公式（希尔记法）:
C26H24NP
化学文摘社编号:
240417-00-9
分子量:
381.45
UNSPSC Code:
12352116
PubChem Substance ID:
329761783
NACRES:
NA.22
MDL number:
MFCD03094578

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产品名称

PhDave-Phos, 97%

SMILES string

CN(C)c1ccccc1-c2ccccc2P(c3ccccc3)c4ccccc4

InChI

1S/C26H24NP/c1-27(2)25-19-11-9-17-23(25)24-18-10-12-20-26(24)28(21-13-5-3-6-14-21)22-15-7-4-8-16-22/h3-20H,1-2H3

InChI key

JGFXUYLYPITYGR-UHFFFAOYSA-N

assay

97%

form

powder

reaction suitability

reaction type: Cross Couplings
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: ligand
reaction type: C-C Bond Formation

mp

122-126 °C

functional group

phosphine

Quality Level

100

相关类别

Application

Buchwald膦配体的更多信息

二烷基联芳基膦配体常用于各种环境中的钯催化反应。

Legal Information

用法以美国专利 6307087 和 6395916 为准。

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SHBP2456
SHBM8316
SHBJ3094
SHBG7841V
SHBG7735V

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David S Surry et al.
Angewandte Chemie (International ed. in English), 47(34), 6338-6361 (2008-07-30)
Palladium-catalyzed amination reactions of aryl halides have undergone rapid development in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl phosphanes have proven to provide especially active catalysts in this context. This Review discusses
Ruben Martin et al.
Accounts of chemical research, 41(11), 1461-1473 (2008-07-16)
The cores of many types of polymers, ligands, natural products, and pharmaceuticals contain biaryl or substituted aromatic structures, and efficient methods of synthesizing these structures are crucial to the work of a broad spectrum of organic chemists. Recently, Pd-catalyzed carbon-carbon
David S Surry et al.
Chemical science, 2(1), 27-50 (2011-01-01)
Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This review attempts to aid the reader in the selection of the best choice of reaction conditions and ligand

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Buchwald Phosphine Ligands

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