696307
氯[1,3-双(2,6-二异丙基苯基)咪唑-2-亚基]铜(I)
powder
别名:
[(iPr)CuCl], [1,3-双(2,6-二异丙基苯基)咪唑-2-亚基]氯化铜(I)
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关于此项目
经验公式（希尔记法）:
C27H36ClCuN2
化学文摘社编号:
分子量:
487.59
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
氯[1,3-双(2,6-二异丙基苯基)咪唑-2-亚基]铜(I),
form
powder
Quality Level
reaction suitability
core: copper, reagent type: catalyst
mp
>300 °C
SMILES string
CC(C)c1cccc(C(C)C)c1N2C=CN(\C2=[Cu]\Cl)c3c(cccc3C(C)C)C(C)C
InChI
1S/C27H36N2.ClH.Cu/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;;/h9-16,18-21H,1-8H3;1H;/q;;+1/p-1
InChI key
JPUFNIIPFXQOCB-UHFFFAOYSA-M
Application
"用于烯烃和羰基的还原、卡宾转移反应、烯烃氮杂环丙化反应和醛类亚甲基化反应。"
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
商品
N-Heterocyclic Carbene-Copper Complexes
设计全新的金属催化络合物时，N-杂环卡宾配体(NHCs)是绝佳选择。这些催化剂具有空气和水分稳定性，可作为前体用于合成更多空气敏感复合物。
Kaur H. et al.
Organometallics, 23, 1157-1157 (2004)
Manuel R Fructos et al.
Journal of the American Chemical Society, 126(35), 10846-10847 (2004-09-02)
The complex IPrCuCl (1) catalyzes the transfer of the :CHCO2Et group from ethyl diazoacetate (EDA) to unsaturated and saturated substrates (olefins, amine, alcohols) with very high yields. In the absence of substrate, the complex 1 does not react with EDA
Hélène Lebel et al.
The Journal of organic chemistry, 72(1), 144-149 (2006-12-30)
(NHC)-Cu (NHC = N-heterocyclic carbene) complexes efficiently catalyzed the methylenation of a variety of aliphatic and aromatic aldehydes and ketones in the presence of trimethylsilyldiazomethane, triphenylphosphine, and 2-propanol. The copper catalysts are not only inexpensive compared to rhodium complexes, but
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 696307-1G | 04061826700686 |
| 696307-250MG | 04061833550885 |