696668
氯化镍(II)乙二醇二甲基醚络合物
98%, powder
别名:
二氯（二甲氧基乙烷）镍, NiCl2 甘醇二甲醚
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关于此项目
线性分子式:
NiCl2:CH3OCH2CH2OCH3
化学文摘社编号:
分子量:
219.72
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
氯化镍(II)乙二醇二甲基醚络合物, 98%
Quality Level
assay
98%
form
powder
reaction suitability
core: nickel, reagent type: catalyst
mp
>300 °C
SMILES string
Cl[Ni]Cl.COCCOC
InChI
1S/C4H10O2.2ClH.Ni/c1-5-3-4-6-2;;;/h3-4H2,1-2H3;2*1H;/q;;;+2/p-2
InChI key
OCMNCWNTDDVHFK-UHFFFAOYSA-L
Application
氯化镍(II)乙二醇二甲基醚络合物可用于：
- 用作外消旋苄基氯的硼化反应的催化剂，以合成对映体富集的苄基硼酸酯。
- 用作烷基碘的三氟甲基化的启动剂，以合成多种烷基CF3化合物。
- 合成双（苯并咪唑-2-亚苄基）镍钳形配合物，可用于将CO2电催化还原为CO。
- 用作路易斯酸催化剂，通过可见光的光活化作用C-酰化β-酮酸酯。
signalword
Danger
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Classifications
Acute Tox. 3 Oral - Aquatic Acute 1 - Carc. 1B - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Water-react. 2
商品
Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.
Catalyst-Controlled Regioselective Acylation of ?-Ketoesters with ?-Diazo Ketones Induced by Visible Light.
Liu D, et al.
Organic Letters, 20(22), 7278-7282 (2018)
Synthesis and comparison of nickel, palladium, and platinum bis (N-heterocyclic carbene) pincer complexes for electrocatalytic CO 2 reduction.
Therrien JA, et al.
Dalton Transactions, 47(6), 1827-1840 (2018)
Amanda Grass et al.
Dalton transactions (Cambridge, England : 2003), 50(7), 2501-2509 (2021-01-31)
Reaction of LiOCtBu2Ph with TlPF6 forms the dimeric Tl2(OCtBu2Ph)2 complex, a rare example of a homoleptic thallium alkoxide complex demonstrating formally two-coordinate metal centers. Characterization of Tl2(OCtBu2Ph)2 by 1H and 13C NMR spectroscopy and X-ray crystallography reveals the presence of
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 696668-1G | 04061832785615 |
| 696668-5G | 04061833550892 |