Merck
CN

697079

Sigma-Aldrich

四氯化钛

packaged for use in deposition systems

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别名:
氯化钛(IV), TTC, 四氯化钛
线性分子式:
TiCl4
CAS号:
分子量:
189.68
EC 号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.23

蒸汽压

50 mmHg ( 55 °C)
9.6 mmHg ( 20 °C)

质量水平

检测方案

≥99.995% (trace metals analysis)

形式

liquid

反应适用性

core: titanium
reagent type: catalyst

bp

135-136 °C (lit.)

mp

−25 °C (lit.)

密度

1.73 g/mL at 20 °C (lit.)

SMILES字符串

Cl[Ti](Cl)(Cl)Cl

InChI

1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4

InChI key

XJDNKRIXUMDJCW-UHFFFAOYSA-J

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一般描述

基础材料的原子序数:22钛

应用

四氯化钛可用于通过氧化作用气相合成二氧化钛粉末。 它可用作交叉和不对称羟醛缩合反应的催化剂。四氯化钛的其它可能用途是合成:
  • γ来自烯丙基硅烷和羰基化合物的δ不饱和醇,
  • 来自芳香醛的N-膦酰亚胺和N-磺酰亚胺,
  • 来自烯丙基硅烷和缩醛的高烯丙基醚。6

象形图

CorrosionSkull and crossbones

警示用语:

Danger

危险声明

危险分类

Acute Tox. 1 Inhalation - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

靶器官

Respiratory system

补充剂危害

储存分类代码

6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 1

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

新产品

分析证书(COA)

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示例

T1503
货号
-
25G
包装规格/数量

其它示例:

705578-5MG-PW

PL860-CGA/SHF-1EA

MMYOMAG-74K-13

1000309185

输入内容 1.000309185)

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索取COA

  1. Which document(s) contains shelf-life or expiration date information for a given product?

    If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis.

  2. How do I get lot-specific information or a Certificate of Analysis?

    The lot specific COA document can be found by entering the lot number above under the "Documents" section.

  3. How do I find price and availability?

    There are several ways to find pricing and availability for our products. Once you log onto our website, you will find the price and availability displayed on the product detail page. You can contact any of our Customer Sales and Service offices to receive a quote.  USA customers:  1-800-325-3010 or view local office numbers.

  4. What is the Department of Transportation shipping information for this product?

    Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product. 

  5. Can the empty deposition cylinders be refilled?

    Yes, we are able to refill these cylinders through our SAFC Hitech group.  Please contact our Technical Service department by email at techserv@sial.com, and they will forward you to the appropriate SAFC Hitech representative for a quote.

  6. My question is not addressed here, how can I contact Technical Service for assistance?

    Ask a Scientist here.

New cross-aldol reactions. Reactions of silyl enol ethers with carbonyl compounds activated by titanium tetrachloride
Mukaiyama T, et al.
Journal of the American Chemical Society, 96(24), 7503-7509 null
M T Crimmins et al.
The Journal of organic chemistry, 66(3), 894-902 (2001-06-30)
Asymmetric aldol additions using chlorotitanium enolates of N-acyloxazolidinone, oxazolidinethione, and thiazolidinethione propionates proceed with high diastereoselectivity for the Evans or non-Evans syn product depending on the nature and amount of the base used. With 1 equiv of titanium tetrachloride and
The titanium tetrachloride induced synthesis of N-phosphinoylimines and N-sulphonylimines directly from aromatic aldehydes
Jennings WB and Lovely CJ
Tetrahedron, 47(29), 5561-5568 (1991)
Syntheses of γ,δ-unsaturated alcohols from allylsilanes and carbonyl compounds in the presence of titanium tetrachloride
Hosomi A and Sakurai H
Tetrahedron Letters, 17(16), 1295-1298 (1976)
Ravit Madar et al.
Brain, behavior, and immunity, 48, 301-312 (2015-05-30)
Neuroinflammation in the central nervous system is detrimental for learning and memory, as evident form epidemiological studies linking developmental defects and maternal exposure to harmful pathogens. Postnatal infections can also induce neuroinflammatory responses with long-term consequences. These inflammatory responses can

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