产品名称
氰化亚铜双(氯化锂)络合物 溶液, in anhydrous tetrahydrofuran
form
liquid
Quality Level
reaction suitability
core: copper, reagent type: catalyst
concentration
in anhydrous tetrahydrofuran
density
0.999 g/mL at 25 °C
SMILES string
[Li]Cl.[Li]Cl.[Cu]C#N
InChI
1S/CN.2ClH.Cu.2Li/c1-2;;;;;/h;2*1H;;;/q;;;;2*+1/p-2
InChI key
QGXKBLXNBYNHBV-UHFFFAOYSA-L
Application
氰化亚铜（I）二（氯化锂）配合物可用于，通过有机锌 和格氏（Grignard）试剂的转移金属化合成有机铜（I）试剂。 也是制备有机铜（I）试剂的有用前体。
signalword
Danger
Hazard Classifications
Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Central nervous system, Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
1.4 °F - closed cup - Solvent
flash_point_c
-17 °C - closed cup - Solvent
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Regioselective functionalization of trisubstituted pyridines using a bromine-magnesium exchange.
Ren H and Knochel P
Chemical Communications (Cambridge, England), 11(7), 726-728 (2006)
TMPZnCl?LiCl: A new active selective base for the directed zincation of sensitive aromatics and heteroaromatics.
Mosrin M and Knochel P
Organic Letters, 11(8), 1837-1840 (2009)
Joel M Harris et al.
The Journal of organic chemistry, 68(11), 4371-4381 (2003-05-24)
2,5,6-Trisubstituted piperidines are readily prepared by a combination of an aza-Achmatowicz oxidation of a furyl-substituted benzenesulfonamide followed by a conjugate addition to the resulting 2H-pyridone and subsequent addition of various nucleophiles to a transient N-sulfonyliminium ion. The stereochemistry of the
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 697257-50ML | 04061832786315 |