697257
氰化亚铜双(氯化锂)络合物 溶液
in anhydrous tetrahydrofuran, liquid
别名:
Copper(I) cyanide di(lithium chloride)
产品名称
氰化亚铜双(氯化锂)络合物 溶液, in anhydrous tetrahydrofuran
SMILES string
[Li]Cl.[Li]Cl.[Cu]C#N
InChI
1S/CN.2ClH.Cu.2Li/c1-2;;;;;/h;2*1H;;;/q;;;;2*+1/p-2
InChI key
QGXKBLXNBYNHBV-UHFFFAOYSA-L
form
liquid
reaction suitability
core: copper
reagent type: catalyst
concentration
in anhydrous tetrahydrofuran
density
0.999 g/mL at 25 °C
Quality Level
Application
氰化亚铜（I）二（氯化锂）配合物可用于，通过有机锌 和格氏（Grignard）试剂的转移金属化合成有机铜（I）试剂。 也是制备有机铜（I）试剂的有用前体。
signalword
Danger
Hazard Classifications
Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Central nervous system, Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
1.4 °F - closed cup - Solvent
flash_point_c
-17 °C - closed cup - Solvent
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Regioselective functionalization of trisubstituted pyridines using a bromine-magnesium exchange.
Ren H and Knochel P
Chemical Communications (Cambridge, England), 11(7), 726-728 (2006)
TMPZnCl?LiCl: A new active selective base for the directed zincation of sensitive aromatics and heteroaromatics.
Mosrin M and Knochel P
Organic Letters, 11(8), 1837-1840 (2009)
Joel M Harris et al.
The Journal of organic chemistry, 68(11), 4371-4381 (2003-05-24)
2,5,6-Trisubstituted piperidines are readily prepared by a combination of an aza-Achmatowicz oxidation of a furyl-substituted benzenesulfonamide followed by a conjugate addition to the resulting 2H-pyridone and subsequent addition of various nucleophiles to a transient N-sulfonyliminium ion. The stereochemistry of the
Tomas Hudlicky et al.
The Journal of organic chemistry, 67(25), 8726-8743 (2002-12-07)
Biocatalytic approaches have yielded efficient total syntheses of the major Amaryllidaceae alkaloids, all based on the key enzymatic dioxygenation of suitable aromatic precursors. This paper discusses the logic of general synthetic design for lycoricidine, narciclasine, pancratistatin, and 7-deoxypancratistatin. Experimental details
Krause, N.; Gerold, A.
Angewandte Chemie (International Edition in English), 36, 186-186 (1997)
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