Merck
CN

697575

Sigma-Aldrich

(乙腈)[(2-联苯)二叔丁基膦]六氟锑酸金(I)

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别名:
JohnPhos Au(MeCN)SbF6
Empirical Formula (Hill Notation):
C22H30AuF6NPSb
分子量:
772.17
MDL编号:
PubChem化学物质编号:
NACRES:
NA.22

形式

solid

质量水平

reaction suitability

core: gold
reagent type: catalyst

mp

198-203 °C (D)

SMILES string

[Au+].CC#N.F[Sb-](F)(F)(F)(F)F.CC(C)(C)P(c1ccccc1-c2ccccc2)C(C)(C)C

InChI

1S/C20H27P.C2H3N.Au.6FH.Sb/c1-19(2,3)21(20(4,5)6)18-15-11-10-14-17(18)16-12-8-7-9-13-16;1-2-3;;;;;;;;/h7-15H,1-6H3;1H3;;6*1H;/q;;+1;;;;;;;+5/p-6

InChI key

ADQOZROJMVWPRI-UHFFFAOYSA-H

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reaction suitability

core: gold, reagent type: catalyst

reaction suitability

core: gold, reagent type: catalyst

reaction suitability

core: gold, reagent type: catalyst

reaction suitability

core: gold, reagent type: catalyst

mp

198-203 °C (D)

mp

162-167 °C (decomposition)

mp

>300 °C

mp

237-240 °C

一般描述

(乙腈)[(2-联苯)二叔丁基膦]六氟锑酸金(I) 是一种磷化氢连接的金(I)复合物。它可用作多米诺反应的催化剂,用于形成C–C、C–N和C–O 键,因为其容易激活C=C 和C≡C键,从而产生独特的重排结构或者与各种亲核试剂反应。金催化剂提供了一种温和地构建复杂化学结构的良好方法,采用其它反应模式则难以实现这一点。

象形图

Exclamation markEnvironment

警示用语:

Warning

危险声明

危险分类

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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