703540
2,2,6,6-四甲基哌啶基氯化镁氯化锂复合物 溶液
1.0 M in THF
别名:
TMPMgCl·LiCl
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关于此项目
经验公式(希尔记法):
C9H18Cl2LiMgN
化学文摘社编号:
分子量:
242.40
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22
表单
liquid
质量水平
反应适用性
reaction type: Grignard Reaction
浓度
1.0 M in THF
20 % (w/w)
密度
0.96 g/mL at 25 °C
储存温度
2-8°C
SMILES字符串
[Li+].[Cl-].CC1(C)CCCC(C)(C)N1[Mg]Cl
InChI
1S/C9H18N.2ClH.Li.Mg/c1-8(2)6-5-7-9(3,4)10-8;;;;/h5-7H2,1-4H3;2*1H;;/q-1;;;+1;+2/p-2
InChI key
JHBZAAACZVPPRQ-UHFFFAOYSA-L
应用
2,2,6,6-四甲基哌啶基氯化镁氯化锂复合物是非亲核性Knochel-Hauser碱, 主要用于官能化芳烃和杂芳烃的氧化,以制备相应的格氏试剂。它还可以用作通过催化剂转移缩聚合成Π-共轭聚合物过程的碱。
包装
建议将25 mL Sure/Seal™ 瓶作为一次性包装瓶使用。 反复穿刺可能导致产品性能下降。
法律信息
Albemarle US Inc.产品
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
警示用语:
Danger
危险分类
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT SE 3
靶器官
Respiratory system
补充剂危害
储存分类代码
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 3
闪点(°F)
5.0 °F
闪点(°C)
-15 °C
法规信息
危险化学品
此项目有
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商品
Transformative reagents enable selective conversions within molecules containing sensitive functionalities under mild reactions.
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