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Merck
CN

703540

2,2,6,6-四甲基哌啶基氯化镁氯化锂复合物 溶液

1.0 M in THF

别名:

TMPMgCl·LiCl

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关于此项目

经验公式(希尔记法):
C9H18Cl2LiMgN
化学文摘社编号:
分子量:
242.40
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
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form

liquid

Quality Level

reaction suitability

reaction type: Grignard Reaction

packaging

Sure/Seal of

concentration

1.0 M in THF, 20 % (w/w)

density

0.96 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

[Li+].[Cl-].CC1(C)CCCC(C)(C)N1[Mg]Cl

InChI

1S/C9H18N.2ClH.Li.Mg/c1-8(2)6-5-7-9(3,4)10-8;;;;/h5-7H2,1-4H3;2*1H;;/q-1;;;+1;+2/p-2

InChI key

JHBZAAACZVPPRQ-UHFFFAOYSA-L

Application

2,2,6,6-四甲基哌啶基氯化镁氯化锂复合物是非亲核性Knochel-Hauser碱, 主要用于官能化芳烃和杂芳烃的氧化,以制备相应的格氏试剂。它还可以用作通过催化剂转移缩聚合成Π-共轭聚合物过程的碱。

Packaging

建议将25 mL Sure/Seal 瓶作为一次性包装瓶使用。 反复穿刺可能导致产品性能下降。

Legal Information

Albemarle US Inc.产品
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC


signalword

Danger

supp_hazards

存储类别

4.3 - Hazardous materials which set free flammable gases upon contact with water

flash_point_f

5.0 °F

flash_point_c

-15 °C

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

target_organs

Central nervous system, Respiratory system

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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商品

Transformative reagents enable selective conversions within molecules containing sensitive functionalities under mild reactions.


Hiroki Iguchi et al.
Scientific reports, 7, 39937-39937 (2017-01-07)
Processing and manipulation of highly conductive pristine graphene in large quantities are still major challenges in the practical application of graphene for electric device. In the present study, we report the liquid-phase exfoliation of graphite in toluene using well-defined poly(3-hexylthiophene)
Direct, regioselective N-alkylation of 1, 3-azoles.
Chen S
Organic Letters, 18(1), 16-19 (2015)
Highly Functionalized Benzene Syntheses by Directed Mono or Multiple Magnesiations with TMPMgCl.LiCl.
Lin W
Organic Letters, 8(24), 5673-5676 (2006)



全球贸易项目编号

货号GTIN
703540-100ML04061832821443
703540-4X25ML04061832821481
703540-500ML04061838136459