登录 查看组织和合同定价。
选择尺寸
关于此项目
经验公式(希尔记法):
C9H18Cl2LiMgN
化学文摘社编号:
分子量:
242.40
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
InChI
1S/C9H18N.2ClH.Li.Mg/c1-8(2)6-5-7-9(3,4)10-8;;;;/h5-7H2,1-4H3;2*1H;;/q-1;;;+1;+2/p-2
SMILES string
[Li+].[Cl-].CC1(C)CCCC(C)(C)N1[Mg]Cl
InChI key
JHBZAAACZVPPRQ-UHFFFAOYSA-L
form
liquid
reaction suitability
reaction type: Grignard Reaction
concentration
1.0 M in THF, 20 % (w/w)
density
0.96 g/mL at 25 °C
storage temp.
2-8°C
Quality Level
Application
2,2,6,6-四甲基哌啶基氯化镁氯化锂复合物是非亲核性Knochel-Hauser碱, 主要用于官能化芳烃和杂芳烃的氧化,以制备相应的格氏试剂。它还可以用作通过催化剂转移缩聚合成Π-共轭聚合物过程的碱。
Packaging
建议将25 mL Sure/Seal™ 瓶作为一次性包装瓶使用。 反复穿刺可能导致产品性能下降。
Legal Information
Albemarle US Inc.产品
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
5.0 °F
flash_point_c
-15 °C
法规信息
危险化学品
此项目有
Hiroki Iguchi et al.
Scientific reports, 7, 39937-39937 (2017-01-07)
Processing and manipulation of highly conductive pristine graphene in large quantities are still major challenges in the practical application of graphene for electric device. In the present study, we report the liquid-phase exfoliation of graphite in toluene using well-defined poly(3-hexylthiophene)
Direct, regioselective N-alkylation of 1, 3-azoles.
Chen S
Organic Letters, 18(1), 16-19 (2015)
Highly Functionalized Benzene Syntheses by Directed Mono or Multiple Magnesiations with TMPMgCl.LiCl.
Lin W
Organic Letters, 8(24), 5673-5676 (2006)
Scaleable preparation of functionalized organometallics via directed ortho metalation using Mg-and Zn-amide bases.
Wunderlich SH
Organic Process Research & Development, 14(2), 339-345 (2010)
Conjugated Polymers with Repeated Sequences of Group 16 Heterocycles Synthesized through Catalyst-Transfer Polycondensation.
Tsai CH
Journal of the American Chemical Society, 138(21), 6798-6804 (2016)
商品
Transformative reagents enable selective conversions within molecules containing sensitive functionalities under mild reactions.
我们的科学家团队拥有各种研究领域经验,包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持


