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Merck
CN

710857

三氯化铁 溶液

greener alternative

0.2 M in 2-methyltetrahydrofuran, solution

别名:

氯化铁 溶液

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关于此项目

线性分子式:
FeCl3
化学文摘社编号:
分子量:
162.20
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
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产品名称

三氯化铁 溶液, 0.2 M in 2-methyltetrahydrofuran

form

solution

Quality Level

reaction suitability

core: iron, reagent type: catalyst

greener alternative product characteristics

Safer Solvents and Auxiliaries
Use of Renewable Feedstocks
Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

concentration

0.2 M in 2-methyltetrahydrofuran

refractive index

n20/D 1.414

density

0.868 g/mL at 25 °C

greener alternative category

SMILES string

Cl[Fe](Cl)Cl

InChI

1S/3ClH.Fe/h3*1H;/q;;;+3/p-3

InChI key

RBTARNINKXHZNM-UHFFFAOYSA-K

General description

我们致力于为您带来更加绿色的替代产品,这些产品遵守一项或多项绿色化学12项原则。凭借独特的性质,如无毒、低成本、丰度高、选择性高,FeCl3可用于许多生物质转化过程。该产品在2-甲基四氢呋喃中的浓度为0.2 M,因此符合“更安全的溶剂和助剂”、“可再生原料的使用”原则,并提高了催化效率。点击此处以获取更多信息。

Application

溶于绿色溶剂2-甲基四氢呋喃 (2-MeTHF) 中的氯化铁(III)可用于:
  • 作为酚醛偶联反应的温和氧化剂
  • 用于芳基锂和酮烯醇化物的二聚体化
  • 作为一种温和的路易斯酸催化剂催化烯反应
  • Nazarov环化、迈克尔加成和丙酮化反应


2-甲基四氢呋喃(2-MeTHF): 一种生物质衍生的溶剂,广泛应用于有机化学


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signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Irrit. 2

supp_hazards

存储类别

3 - Flammable liquids

wgk

WGK 2

flash_point_f

14.0 °F - closed cup

flash_point_c

-10.0 °C - closed cup

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Chen-Yu Chen et al.
Clinica chimica acta; international journal of clinical chemistry, 438, 337-341 (2014-10-05)
Insulin-like growth factor binding protein-1 (IGFBP-1) constitutes a subgroup of the insulin-like growth factor binding protein systems, and its concentration in amniotic fluid is 100-1000 times higher than the concentration in other body fluids. The aim of this study was
Abdelwareth A O Sarhan et al.
Chemical Society reviews, 38(9), 2730-2744 (2009-08-20)
In this critical review, the use of iron(III) chloride in oxidative C-C couplings of arenes and related unsaturated compounds is presented and reviewed. The approach allows highly selective dimerisations of phenol derivatives, naphthols, and heterocyclic compounds. Sequential couplings give access
D C Florian Wieland et al.
Colloids and surfaces. B, Biointerfaces, 109, 74-81 (2013-04-27)
The early stages of the formation of inorganic aggregates, composed of iron compounds at the solution-air interface, were investigated in situ. The properties of the solution-air interface were changed by using different Langmuir layers. In order to get insight into



全球贸易项目编号

货号GTIN
710857-50ML04061832843605