718114
氯化锰(II)双(氯化锂)络合物 溶液
0.5 M in THF, liquid, density: 95%6 g/mL at 25 °C
别名:
四氯锰酸(II)锂 溶液, 氯化锂锰, 氯锰酸(II)锂, 氯化锰(II)双(氯化锂)络合物 溶液
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关于此项目
线性分子式:
Li2MnCl4
化学文摘社编号:
分子量:
210.63
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
氯化锰(II)双(氯化锂)络合物 溶液, 0.5 M in THF, density: 0.956 g/mL at 25 °C
SMILES string
[Li+].[Li+].Cl[Mn--](Cl)(Cl)Cl
InChI key
VJOUQNFWQPCDPE-UHFFFAOYSA-J
InChI
1S/4ClH.2Li.Mn/h4*1H;;;/q;;;;2*+1;+2/p-4
form
liquid
reaction suitability
core: manganese, reagent type: catalyst
concentration
0.5 M in THF
density
0.956 g/mL at 25 °C
Quality Level
Application
Catalyst for homocoupling of Grignard reagents using atmospheric oxygen as an oxidant
Reactant for:
Reagent for the preparation of Rieke manganese
Reactant for:
- Transmetalation reactions
- Nickel-imidazolium carbene-catalyzed coupling reactions
Reagent for the preparation of Rieke manganese
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
1.4 °F - closed cup
flash_point_c
-17.0 °C - closed cup
法规信息
危险化学品
此项目有
A. Leleu, et al.,
Advanced Synthesis & Catalysis, 348, 1086-1092 (2006)
Manganese- or iron-catalyzed homocoupling of grignard reagents using atmospheric oxygen as an oxidant.
Gérard Cahiez et al.
Journal of the American Chemical Society, 129(45), 13788-13789 (2007-10-20)
A. Eloi, et al.,
Organometallics, 28, 925-928 (2009)
José M Concellón et al.
The Journal of organic chemistry, 72(21), 7974-7979 (2007-09-25)
A complete E-selective synthesis of alpha,beta-unsaturated amides through a sequential reaction of a range of dichloroamides with a variety of aldehydes promoted by Rieke manganese (Mn*) is reported. A mechanism based on a sequential aldol-type reaction and a completely stereoselective
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