重结晶乙酸钯(II)

Name: 重结晶乙酸钯(II)
Brand: ALDRICH

97%, powder

别名:

Pd(OAc)₂

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所有图片(1)

About This Item

线性分子式:

Pd(OCOCH₃)₂

CAS Number:

3375-31-3

分子量:

224.51

EC 号:

222-164-4

MDL编号:

MFCD00012453

UNSPSC代码:

12161600

PubChem化学物质编号:

329763696

NACRES:

NA.22

Product Name

重结晶乙酸钯(II), 97%

质量水平

100

方案

97%

表单

powder

反应适用性

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

mp

227-231 °C

SMILES字符串

CC(=O)O[Pd]OC(C)=O

InChI

1S/2C2H4O2.Pd/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2

InChI key

YJVFFLUZDVXJQI-UHFFFAOYSA-L

一般描述

Palladium(II)acetate, recrystallized, is commonly used as a catalyst in cross-coupling reactions. Prominent applications include the Buchwald-Hartwigamination reaction, Heck reaction, Suzuki coupling, Stille coupling, Sonogashira coupling, and Negishi coupling reactions.

应用

Palladium(II) acetate, recrystallized can be used as a catalyst:

In Stille cross-coupling reaction between benzylic halides and aryl tributyltin to synthesize diarylmethane derivatives in the presence of phosphine ligand.
For the α-arylation of ketones with aryl halides to synthesize arylmethyl ketones in the presence of n-butylbis(1-adamantyl)-phosphine ligand.
In Suzuki-Miyaura cross-coupling reaction between aryl bromides and aryl boronic acids to synthesize biaryl derivatives in the presence of phosphane ligand.
In Buchwald-Hartwig amination reaction between aryl chlorides and anilines to synthesize arylated anilines in the presence of N-heterocyclic carbene ligand.