728551
双[(2-二甲氨基)苯基]胺氯化镍(II)
≥97% (AT), lumps
别名:
Nickamine, 氯[N2-[2-(二甲氨基-κN)苯基]-N1,N1-二甲基-1,2-苯二胺-κN1,κN2]-镍
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关于此项目
经验公式（希尔记法）:
C16H20ClN3Ni
CAS Number:
分子量:
348.50
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22
Product Name
双[(2-二甲氨基)苯基]胺氯化镍(II), ≥97% (AT)
质量水平
方案
≥97% (AT)
表单
lumps
反应适用性
core: nickel
reagent type: catalyst
SMILES字符串
CN(C)c1ccccc1N([Ni]Cl)c2ccccc2N(C)C
InChI
1S/C16H20N3.ClH.Ni/c1-18(2)15-11-7-5-9-13(15)17-14-10-6-8-12-16(14)19(3)4;;/h5-12H,1-4H3;1H;/q-1;;+2/p-1
InChI key
IRLHVNUEEKJBEL-UHFFFAOYSA-M
相关类别
应用
Catalyst for:
Reactant of pincer NN2 ligand leading to selective carbon-carbon bond formation
- Alkyl-alkyl Kumada coupling of secondary alkyl halides
- Direct alkylation of heterocyclic C-H bonds
- Sonogashira coupling of nonactivated alkyl halides
- Kumada-Corriu-Tamao coupling of nonactivated alkyl halides with aryl and heteroaryl nucleophiles
Reactant of pincer NN2 ligand leading to selective carbon-carbon bond formation
包装
Bottomless glass bottle. Contents are inside inserted fused cone.
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
Oleg Vechorkin et al.
Angewandte Chemie (International ed. in English), 48(16), 2937-2940 (2009-01-29)
Reacting in the 'Ni'ck of time: The title reaction is realized by using an isolated Ni(II) complex (1). The catalysis tolerates a wide range of important functional groups that are often incompatible with Grignard reagents in cross-coupling reactions.
Zsolt Csok et al.
Journal of the American Chemical Society, 130(26), 8156-8157 (2008-06-06)
A new pincer-type bis(amino)amine (NN2) ligand and its lithium and nickel complexes, including Ni(II) methyl, ethyl, and phenyl complexes, were synthesized. The Ni(II) alkyl complexes react cleanly with alkyl halides including chlorides to form C-C coupled products and Ni(II) halides.
商品
Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.
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