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Merck
CN

731382

(2R,2′R-(+)-[N,N′-双(2-吡啶基甲基)]-2,2′-联吡咯烷双(乙腈)六氟锑酸铁(II)

greener alternative

powder

别名:

Fe(R,R-PDP), Iron(II) (R,R-(2-({(R)-2-[(R)-1-(pyridin-2-ylmethyl)pyrrolidin-2-yl]pyrrolidin-1-yl}methyl)pyridine)(bis-acetonitrile) hexafluoroantimonate, White-Chen catalyst, [Fe(R,R-PDP)(CH3CN)2](SbF6)2

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关于此项目

经验公式(希尔记法):
C24H32F12FeN6Sb2
化学文摘社编号:
分子量:
931.90
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
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产品名称

(2R,2′R-(+)-[N,N′-双(2-吡啶基甲基)]-2,2′-联吡咯烷双(乙腈)六氟锑酸铁(II),

form

powder

Quality Level

reaction suitability

core: iron, reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

215-226 °C

greener alternative category

SMILES string

[Fe++].CC#N.CC#N.F[Sb-](F)(F)(F)(F)F.F[Sb-](F)(F)(F)(F)F.C1C[C@H]([C@H]2CCCN2Cc3ccccn3)N(C1)Cc4ccccn4

InChI

1S/C20H26N4.2C2H3N.12FH.Fe.2Sb/c1-3-11-21-17(7-1)15-23-13-5-9-19(23)20-10-6-14-24(20)16-18-8-2-4-12-22-18;2*1-2-3;;;;;;;;;;;;;;;/h1-4,7-8,11-12,19-20H,5-6,9-10,13-16H2;2*1H3;12*1H;;;/q;;;;;;;;;;;;;;;+2;2*+5/p-12/t19-,20-;;;;;;;;;;;;;;;;;/m1................./s1

InChI key

XUNWHBGEOCZDBX-QSKJABRXSA-B

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here.

Application

Catalyst for greener ketone synthesis by selective C-H oxidation of methylenes.

Combined Effects on Selectivity in Fe-Catalyzed Methylene Oxidation


pictograms

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signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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历史批次信息供参考:

分析证书(COA)

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全球贸易项目编号

货号GTIN
731382-100MG04061833240298
731382-500MG04061833240304