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Merck
CN

732117

Pd-PEPPSI-IPent催化剂

≥95%, solid

别名:

[1,3-双(2,6-二-3-戊基苯基)咪唑-2-亚基](3-氯吡啶基)二氯化钯(II)

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关于此项目

经验公式(希尔记法):
C40H56Cl3N3Pd
化学文摘社编号:
分子量:
791.67
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
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产品名称

Pd-PEPPSI-IPent催化剂, ≥95%

Quality Segment

assay

≥95%

form

solid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
core: palladium

mp

195-201 °C

functional group

NHC

storage temp.

−20°C

SMILES string

Clc1cccnc1.CCC(CC)c2cccc(C(CC)CC)c2N3C=CN(c4c(cccc4C(CC)CC)C(CC)CC)\C3=[Pd](/Cl)Cl

InChI

1S/C35H52N2.C5H4ClN.2ClH.Pd/c1-9-26(10-2)30-19-17-20-31(27(11-3)12-4)34(30)36-23-24-37(25-36)35-32(28(13-5)14-6)21-18-22-33(35)29(15-7)16-8;6-5-2-1-3-7-4-5;;;/h17-24,26-29H,9-16H2,1-8H3;1-4H;2*1H;/q;;;;+2/p-2

InChI key

BCXSKTXOKALLAZ-UHFFFAOYSA-L

General description

Pd-PEPPSI-IPent催化剂是基于钯的催化剂,可用于催化交联反应中的C-N和C- C键形成。

Application

  • Stille偶联反应的催化剂 (eq.1)
  • Negishi偶联反应的催化剂 (eq.2)
  • Suzuki 偶联反应的催化剂(平衡3)
Reaction scheme for Pd catalyst PEPPSI<SUP>™</SUP>-IPent used in cross coupling reaction
对于小规模和高通量用途,产品为ChemBeads (928399

Legal Information

已获得专利,美国专利号7,250,510。由Total Synthesis Ltd独家授权销售。
PEPPSI is a trademark of Total Synthesis Ltd.


pictograms

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signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



历史批次信息供参考:

分析证书(COA)

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