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Merck
CN

751774

Tris(diethylamido)(tert-butylimido)niobium(V)

packaged for use in deposition systems

别名:

(tert)-Butyliminotris(diethylamino)niobium, tris(N-ethylethanaminato)[2-methyl-2-propanaminato(2-)]-niobium, t-Butylimido tris(diethylamido)niobium(V)

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关于此项目

线性分子式:
((CH3)6N)3NbN(CH3)3
化学文摘社编号:
分子量:
380.41
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
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Quality Level

form

liquid

reaction suitability

core: niobium

density

1.015 g/mL at 25 °C

SMILES string

CCN(CC)[Nb](=NC(C)(C)C)(N(CC)CC)N(CC)CC

InChI

1S/C4H9N.3C4H10N.Nb/c1-4(2,3)5;3*1-3-5-4-2;/h1-3H3;3*3-4H2,1-2H3;/q;3*-1;+3

InChI key

CBCDPJRPMPTFKA-UHFFFAOYSA-N

General description

Tris(diethylamido)(tert-butylimido)niobium(V) (TBTDEN) is a volatile, thermally stable liquid used as a niobium precursor for thin-film deposition. It offers high vapor pressure and clean decomposition, making it ideal for applications requiring materials with high dielectric constants and robust barrier layers.

Application

Tris(diethylamido)(tert-butylimido)niobium(V) is used as a niobium precursor
  • In atomic layer deposition to create niobium-doped tin oxide (NTO), a conductive material. These NTO scaffolds provide a large surface area for thin platinum layers, improving electron transfer in dye-sensitized solar cells.
  • In metal-organic chemical vapor deposition (MOCVD) to grow niobium nitride (NbN) thin films. These films, deposited on silicon wafers, offers good conductivity and are suitable for electronic applications such as gate stacks.


pictograms

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signalword

Danger

target_organs

Respiratory system

存储类别

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 3

flash_point_f

26.6 °F - closed cup

flash_point_c

-3 °C - closed cup

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3 - Water-react. 2

法规信息

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商品

Nanocomposite Coatings with Tunable Properties Prepared by Atomic Layer Deposition

The properties of many devices are limited by the intrinsic properties of the materials that compose them.


Arne Baunemann et al.
Dalton transactions (Cambridge, England : 2003), 28(28), 3715-3722 (2008-07-11)
Novel mixed amido/imido/guanidinato complexes of niobium are reported. The complexes were synthesized by insertion of two equivalents of di-isopropylcarbodiimide (i-Pr-cdi) or bis-cyclohexylcarbodiimide (Cy-cdi) respectively, into the niobium-amido bonds of [Nb(NR(2))(3)(N-t-Bu)] (, R = Me; , R = Et) starting out
Chiu; J.-T.; et al
J. Chin. Chem. Soc., 45, 355-355 (1998)
Thiede; T.; et al
Electrochemical Society Transactions, 16, 229-229 (2008)



全球贸易项目编号

货号GTIN
751774-10G04061833339732