Name: [<I>(S,S</I>)-Teth-TsDpen RuCl]
Brand: ALDRICH

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About This Item

经验公式（希尔记法）:

C₃₀H₃₁ClN₂O₂RuS

CAS Number:

851051-43-9

分子量:

620.17

MDL编号:

MFCD16294984

UNSPSC代码:

12352103

PubChem化学物质编号:

329766311

NACRES:

NA.22

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表单

solid

质量水平

100

旋光性

[α]22/D +339°, c = 0.5% in chloroform

反应适用性

core: ruthenium
reagent type: catalyst

mp

260-268 °C

储存温度

2-8°C

SMILES字符串

Cc1ccc(cc1)S(=O)(=O)N2[C@H]([C@@H]([N@@H](CCCc3ccccc3)[Ru]2Cl)c4ccccc4)c5ccccc5

InChI

1S/C30H31N2O2S.ClH.Ru/c1-24-19-21-28(22-20-24)35(33,34)32-30(27-17-9-4-10-18-27)29(26-15-7-3-8-16-26)31-23-11-14-25-12-5-2-6-13-25;;/h2-10,12-13,15-22,29-31H,11,14,23H2,1H3;1H;/q-1;;+2/p-1/t29-,30-;;/m0../s1

InChI key

MDABGVLQRDDWLY-ARDORAJISA-M

应用

[(S,S)-Teth-TsDpen RuCl] is a catalyst for the asymmetric hydrogenation of ketones. It can be used as a catalyst:

In the reduction of a ketone intermediate for the synthesis of esketamine.
In asymmetric hydrogenation of acetylenic ketones.
For the preparation of (3S,6S)-1,8-diphenylocta-1,7-diyne-3,6-diol starting from 1,8-diphenylocta-1,7-diyne-3,6-dione.