752800
[(S,S)-Teth-TsDpen RuCl]
别名:
stereoisomer of Chloro[N-[(1S,2S)-1,2-diphenyl-2-[(R)-[3-(η6-phenyl)propyl]amino-κN]ethyl]-4-methylbenzenesulfonamidato-κN]ruthenium
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关于此项目
经验公式（希尔记法）:
C30H31ClN2O2RuS
化学文摘社编号:
分子量:
620.17
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22
form
solid
Quality Segment
optical activity
[α]22/D +339°, c = 0.5% in chloroform
reaction suitability
core: ruthenium, reagent type: catalyst
mp
260-268 °C
storage temp.
2-8°C
SMILES string
Cc1ccc(cc1)S(=O)(=O)N2[C@H]([C@@H]([N@@H](CCCc3ccccc3)[Ru]2Cl)c4ccccc4)c5ccccc5
InChI
1S/C30H31N2O2S.ClH.Ru/c1-24-19-21-28(22-20-24)35(33,34)32-30(27-17-9-4-10-18-27)29(26-15-7-3-8-16-26)31-23-11-14-25-12-5-2-6-13-25;;/h2-10,12-13,15-22,29-31H,11,14,23H2,1H3;1H;/q-1;;+2/p-1/t29-,30-;;/m0../s1
InChI key
MDABGVLQRDDWLY-ARDORAJISA-M
Application
[(S,S)-Teth-TsDpen RuCl] is a catalyst for the asymmetric hydrogenation of ketones. It can be used as a catalyst:
- In the reduction of a ketone intermediate for the synthesis of esketamine.
- In asymmetric hydrogenation of acetylenic ketones.
- For the preparation of (3S,6S)-1,8-diphenylocta-1,7-diyne-3,6-diol starting from 1,8-diphenylocta-1,7-diyne-3,6-dione.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable