759171
CPhos
98%, solid
别名:
2-二环己基膦-2′,6′-双（ N,N -二甲氨基）联苯
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关于此项目
经验公式（希尔记法）:
C28H41N2P
化学文摘社编号:
分子量:
436.61
UNSPSC Code:
12352116
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
CPhos, 98%
assay
98%
form
solid
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Cross Couplings
mp
108-113 °C
functional group
phosphine
Quality Level
Application
在 3-环戊基吲哚衍生物 二氢苯并呋喃 和 反式 双环磺酰胺的钯催化合成中，CPhos 可作为配体使用
- 。
- 合成环钯配合物预催化剂，用于仲烷基锌的 Negishi 偶联。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Hutt JT and Wolfe JP
Organic Chemistry Frontiers : An International Journal of Organic Chemistry / Royal Society of Chemistry, 3(10), 1314-1318 (2016)
Palladium-Catalyzed Negishi Coupling of ?-CF3 Oxiranyl Zincate: Access to Chiral CF3-Substituted Benzylic Tertiary Alcohols.
Zhang H and Buchwald SL
Journal of the American Chemical Society, 139(33), 11590-11594 (2017)
Negishi coupling of secondary alkylzinc halides with aryl bromides and chlorides.
Han C and Buchwald SL
Journal of the American Chemical Society, 131(22), 7532-7533 (2009)
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