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Merck
CN

759562

三(二甲氨基)硅烷

packaged for use in deposition systems

别名:

三(二甲氨基)硅烷, (Me2N)3SiH, N,N,N′,N′,N′′, N′′-六甲基硅烷三胺, 三(二甲基氨基)硅烷, N,N,N′,N′,N′′′,N′′′-六甲基硅烷三胺, TDMA

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关于此项目

线性分子式:
((CH3)2N)3SiH
化学文摘社编号:
分子量:
161.32
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
EC Number:
239-165-0
MDL number:
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Quality Level

assay

≥99.9% (GC)

form

liquid

bp

142 °C (lit.)

mp

−90 °C (lit.)

density

0.838 g/mL at 25 °C (lit.)

SMILES string

CN(C)[SiH](N(C)C)N(C)C

InChI

1S/C6H19N3Si/c1-7(2)10(8(3)4)9(5)6/h10H,1-6H3

InChI key

TWVSWDVJBJKDAA-UHFFFAOYSA-N

General description

三(二甲氨基)硅烷是一种具有高挥发性和热稳定性的有机硅化合物,广泛用作气相沉积前驱体,制造用于太阳能电池、燃料电池催化剂和半导体等各种应用的含硅薄膜。沉积可以在低衬底温度下进行(<150)。TDMAS的熔点和蒸气压在合适的工作范围内,是非常好的气相沉积前驱体。

Application

三(二甲氨基)硅烷可用于:
  • 作为原子层沉积法将硅酸铝沉积到染料敏化太阳能电池TiO2阳极上的硅源。
  • 作为制造锂离子电池功能化硅增强隔膜的前驱体。



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signalword

Danger

supp_hazards

存储类别

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 3

flash_point_f

16.0 - 32.0 °F - closed cup

flash_point_c

-8.89 - 0.00 °C - closed cup

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - Water-react. 2

法规信息

非剧毒-急性毒性1

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Boudreau; M.; Boumerzoug; M.; Mascher; P.; Jessop; P. E.
Applied Physics Letters, 63, 3014-3014 (1993)
Hirose; F.; Kinoshita; Y.; Shibuya; S.; et al
Thin Solid Films, 519, 270-270 (2011)
B Ballantyne et al.
Toxicology and industrial health, 5(1), 45-54 (1989-01-01)
The acute handling hazards of tris(dimethylamino)silane [TDMAS] were investigated. The acute male rat peroral LD50 (with 95% confidence limits) was 0.71 (0.51-0.97) ml/kg, and the acute male rabbit percutaneous LD50 was 0.57 (0.35-0.92) ml/kg. The liquid was severely irritating to



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货号GTIN
759562-25G04061832916965