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Merck
CN

75991

活性炭负载钯催化剂

greener alternative

5% Pd basis (based on dry substance), paste, moistened with water

别名:

Pd/C

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关于此项目

线性分子式:
Pd
UNSPSC Code:
12161600
PubChem Substance ID:
57652601
NACRES:
NA.22
MDL number:
MFCD03457879

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产品名称

活性炭负载钯催化剂, moistened with water, 5% Pd basis (based on dry substance)

SMILES string

[Pd]

InChI key

KDLHZDBZIXYQEI-UHFFFAOYSA-N

InChI

1S/Pd

form

paste

quality

moistened with water

contains

~50% water as stabilizer

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

greener alternative product characteristics

Designing Safer Chemicals
Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

concentration

5% Pd (based on dry substance)

greener alternative category

, Aligned

Quality Level

100

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相关类别

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Palladium on activated charcoal can be used as a heterogeneous catalyst:
  • To synthesize methyl esters via oxidative esterification of primary alcohols.
  • In the hydrogenation of phenol to cyclohexanone.
  • For carbonylation of iodoanilines with amines and trimethyl orthoformate to prepare quinazolinones.
  • In the hydrodehalogenation of aromatic halides to form arenes in aqueous media.

存储类别

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCP3538
BCCP1902
BCCN7630
BCCN5390
BCCN2685

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Oxidative Esterification of Primary Alcohols with a Pd/Bi/Te Catalyst
Uozumi Y and Osako T
Synfacts, 10, 0108-0108 (2014)
Highly selective palladium supported catalyst for hydrogenation of phenol in aqueous phase
Perez Y, et al.
Catalysis Communications, 12, 1071-1074 (2011)
Pd/C-catalyzed hydrodehalogenation of aromatic halides in aqueous solutions at room temperature under normal pressure.
Xia C
Catalysis Communications, 5(8), 383-386 (2004)
Pd/C as an efficient heterogeneous catalyst for carbonylative four-component synthesis of 4 (3 H)-quinazolinones
Natte K, et al.
Catalysis Science & Technology, 5, 4474-4480 (2015)
Development of GSKDevelopment of GSK's reagent guides ? embedding sustainability into reagent selections reagent guides ? embedding sustainability into reagent selection.
Adams JP, et al.
Green Chemistry, 15, 1542-1549 (2013)

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