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Merck
CN

76063

活性炭负载氢氧化钯

greener alternative

10-20% Pd (based on dry substance), lumps, moistened with water

别名:

Pearlman 催化剂

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关于此项目

UNSPSC Code:
12161600
PubChem Substance ID:
57652615
NACRES:
NA.22
MDL number:
MFCD00064599

主要文件

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产品名称

活性炭负载氢氧化钯, moistened with water, 10-20% Pd basis (based on dry substance)

SMILES string

O[Pd]O

InChI

1S/2H2O.Pd/h2*1H2;/q;;+2/p-2

InChI key

NXJCBFBQEVOTOW-UHFFFAOYSA-L

form

lumps

quality

moistened with water

contains

~50% water as stabilizer

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

greener alternative product characteristics

Designing Safer Chemicals
Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

concentration

10-20% Pd (based on dry substance)

greener alternative category

Aligned

Quality Level

100

相关类别

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalysis. Click here for more information.

Application

氢化反应催化剂
Catalyst for hydrogenolysis of benzyl groups and epoxides; used to reduce nitro compounds to amines and as dehydrogenation reagent.

pictograms

Environment
GHS09

signalword

Warning

hcodes

H410

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCP0808
BCCK5041
1332670V
1332670
1171763

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Jung, M. E.; Choi, Y. M.
The Journal of Organic Chemistry, 56, 6729-6729 (1991)
Zhao, S.; Freeman, J. P.; Szmuszkovicz, J.
The Journal of Organic Chemistry, 57, 4051-4051 (1992)
Prugh, J. D.; Rooney, C. S. et al.
Tetrahedron Letters, 26, 2947-2947 (1985)
Development of GSKDevelopment of GSK's reagent guides ? embedding sustainability into reagent selections reagent guides ? embedding sustainability into reagent selection.
Adams JP, et al.
Green Chemistry, 15, 1542-1549 (2013)

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