form
solution
Quality Segment
reaction suitability
reaction type: Grignard Reaction
packaging
Sure/Seal™ of
concentration
0.5 M in THF
density
0.940 g/mL at 25 °C
functional group
allyl
SMILES string
Br[Mg]CCCC=C
InChI
1S/C5H9.BrH.Mg/c1-3-5-4-2;;/h3H,1-2,4-5H2;1H;/q;;+1/p-1
InChI key
LHTUYNSQNJOCCB-UHFFFAOYSA-M
Application
4-Pentenylmagnesium bromide is a general Grignard reagent used in the total synthesis of (−)-sarain A, (−)-salicylihalamide A and (+)-erysotramidine. It is also used in the synthesis of hexa-peri-hexabenzocoronene cyclophane.
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
flash_point_f
11.8 °F - closed cup
flash_point_c
-11.2 °C - closed cup
target_organs
Central nervous system, Respiratory system
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 1