762504
双[(碘化四丁基铵)碘化铜(I)]
95%, solid
别名:
Tetrabutylammonium iodide copper(I) iodide dimer
产品名称
双[(碘化四丁基铵)碘化铜(I)], 95%
质量水平
方案
95%
表单
solid
反应适用性
core: copper
reagent type: catalyst
mp
90-97 °C
SMILES字符串
[I-].[I-].[Cu]I.[Cu]I.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC
InChI
1S/2C16H36N.2Cu.4HI/c2*1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;;;;;;/h2*5-16H2,1-4H3;;;4*1H/q4*+1;;;;/p-4
InChI key
AVVGGLORWAVEFH-UHFFFAOYSA-J
应用
双[（碘化四丁基铵）碘化铜（I）]可作为催化剂用于：
- 通过三组分点击反应合成 1,4-二取代的 1,2,3-三氮唑。
- 在碳酸钾作为碱的存在下吲哚的 N-芳基化。
- 在碳酸铯和乙腈存在下的 Ullmann 偶联反应。
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
Carmela Molinaro et al.
The Journal of organic chemistry, 84(12), 8006-8018 (2019-05-28)
A practical and efficient enantioselective synthesis of the calcitonin gene-related peptide receptor antagonist 1 has been developed. The key structural component of the active pharmaceutical ingredient is a syn-1,2-amino-fluoropiperidine 4. Two approaches were developed to synthesize this important pharmacophore. Initially
A recyclable and water soluble copper (I)-catalyst: one-pot synthesis of 1, 4-disubstituted 1, 2, 3-triazoles and their biological evaluation
Nekkanti S, et al
Royal Society of Chemistry Advances, 6, 103556-103566 (2016)
A soluble copper (I) source and stable salts of volatile ligands for copper-catalyzed C-X couplings
Maligres P, et al.
The Journal of Organic Chemistry, 77 (2012)
实验方案
KitAlysis™ Cu C-N (Buchwald-Hartwig) cross-coupling high-throughput screening kit. Detailed Set-Up User Guide and a downloadable excel file for calculations.
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