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765953

1,11-二叠氮-3,6,9-三氧杂十一烷

别名:

Azido-PEG3-azido, Bis-PEG3-Azide

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关于此项目

经验公式(希尔记法):
C8H16N6O3
化学文摘社编号:
分子量:
244.25
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352200
MDL number:
Form:
liquid
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form

liquid

Quality Segment

reaction suitability

reaction type: click chemistry, reagent type: cross-linking reagent

refractive index

n20/D 1.470

bp

163-196 °C/760 mmHg

density

1.170 g/mL at 25 °C

storage temp.

−20°C

SMILES string

[N-]=[N+]=NCCOCCOCCOCCN=[N+]=[N-]

InChI

1S/C8H16N6O3/c9-13-11-1-3-15-5-7-17-8-6-16-4-2-12-14-10/h1-8H2

InChI key

SFMMXKLNFMIUCH-UHFFFAOYSA-N

Application

1,11-Diazido-3,6,9-trioxaundecane may be used to synthesize:
  • 1,11-bis[4-(pyren-1-ylmethoxymethyl)-1H-1,2,3-triazole-1-yl]-3,6,9-trioxaundecane, a fluorogenic chemosensor that can selective detect Hg2+ and Ag+ ions in aqueous methanol solution
  • 1-amino-11-azido-3,6,9-trioxaundecane, an intermediate to synthesize tetraethylene glycol based bidentate ligand functionalized with dihydrolipoic acid and biotin (DHLA-TEG-biotin)

Homobifunctional PEG azide click chemistry linker. Azide functional groups will react via a copper catalyzed or strain promoted 1,3-dipolar cycloaddition click reaction with terminal alkynes and cyclooctyne derivatives to yield a stable triazole linkage.


象形图

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警示词

Warning

危险代码

Hazard Classifications

Acute Tox. 4 Oral

存储类别

10 - Combustible liquids

怎么回事?

WGK 3

闪点 (F)

Not applicable

闪点 (°C)

Not applicable



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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