Merck
CN

767654

Sigma-Aldrich

-二氯双(二甲基亚砜)铂(II)

97%

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别名:
-二氯双(二甲基亚砜)铂(II), Pt(DMSO)2Cl2
Empirical Formula (Hill Notation):
C4H12Cl2O2PtS2
CAS号:
分子量:
422.25
MDL编号:
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

97%

形式

solid

reaction suitability

core: platinum
reagent type: catalyst

mp

218-224 °C

SMILES string

Cl[Pt]Cl.CS(C)=O.CS(C)=O

InChI

1S/2C2H6OS.2ClH.Pt/c2*1-4(2)3;;;/h2*1-2H3;2*1H;/q;;;;+2/p-2

InChI key

KDADQDWVKZJTDQ-UHFFFAOYSA-L

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331406275816244945
form

solid

form

powder

form

-

form

-

reaction suitability

core: platinum, reagent type: catalyst

reaction suitability

core: platinum, reagent type: catalyst

reaction suitability

core: platinum, reagent type: catalyst

reaction suitability

core: platinum, reagent type: catalyst

mp

218-224 °C

mp

193-194 °C (lit.)

mp

224 °C (dec.) (lit.)

mp

≥300 °C (lit.)

一般描述

顺式二氯双(二甲基硫亚砜)合铂(II)是一种钯复合物,可用作多种化学反应的催化剂,包括多氟芳基亚胺的甲基化和甲烷氧化。它是一种有效的C-F 活化预催化剂(precatalyst)。

应用

顺式二氯双(二甲基硫亚砜)合铂(II)可用作:
  • 发烟硫酸介导的(SO3-H2SO4)甲烷氧化形成硫酸甲酯(MBS)的催化剂。
  • 环金属复合物合成的前体。

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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二氯化铂

K R Grigorian et al.
Biofizika, 56(1), 31-34 (2011-03-30)
The interaction of cis-[PtCl2(Me2SO)2] with human serum albumin (HSA) and the sensitivity of the complex towards the thermal denaturation depending on the duration of incubation have been studied by absorption and fluorescence spectroscopy methods. Optimum conditions for cis-[PtCl2(Me2SO)2] binding to
R Gorodetsky et al.
Medical physics, 20(4), 1007-1012 (1993-07-01)
Noninvasive analysis of heavy elements in external tissues by diagnostic-x-ray spectrometry (DXS) is presented. Pt can be detected accurately with sensitivity below 1 microgram/g wet weight of tissue. In the present paper the possibility to monitor Pt accumulation and clearance
Treatment of pathological stage T3N+M0 bladder cancer: the case for observation.
D A Corral et al.
Seminars in urology, 11(2), 64-68 (1993-05-01)
B A Teicher et al.
Cancer chemotherapy and pharmacology, 32(4), 315-319 (1993-01-01)
The survival of bone-marrow granulocyte-macrophage colony-forming units (CFU-GM), an alkylating-agent-sensitive normal tissue, was assessed in mice bearing the EMT-6 parental tumor or the in vivo resistant EMT-6/CDDP, EMT-6/CTX, EMT-6/Thio, and EMT-6/Carbo tumors. The survival pattern of the bone-marrow CFU-GM recapitulated
K Nishio et al.
International journal of cancer, 55(4), 616-622 (1993-10-21)
cis-Diamminedichloroplatinum(II) (CDDP) induced G2-phase arrest in PC-9 human cancer cells. To elucidate how CDDP acts on cell-cycle regulation, we analyzed the effect of CDDP on cell-cycle regulators such as p34cdc2 protein kinase. p34cdc2 protein kinase activity was maximum in G2

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