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经验公式(希尔记法):
C4H12Cl2O2PtS2
化学文摘社编号:
分子量:
422.25
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
顺-二氯双(二甲基亚砜)铂(II), 97%
SMILES string
Cl[Pt]Cl.CS(C)=O.CS(C)=O
InChI
1S/2C2H6OS.2ClH.Pt/c2*1-4(2)3;;;/h2*1-2H3;2*1H;/q;;;;+2/p-2
InChI key
KDADQDWVKZJTDQ-UHFFFAOYSA-L
assay
97%
form
solid
reaction suitability
core: platinum
reagent type: catalyst
mp
218-224 °C
Quality Level
Application
顺式二氯双(二甲基硫亚砜)合铂(II)可用作:
- 发烟硫酸介导的(SO3-H2SO4)甲烷氧化形成硫酸甲酯(MBS)的催化剂。
- 环金属复合物合成的前体。
General description
顺式二氯双(二甲基硫亚砜)合铂(II)是一种钯复合物,可用作多种化学反应的催化剂,包括多氟芳基亚胺的甲基化和甲烷氧化。它是一种有效的C-F 活化预催化剂(precatalyst)。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
R Gorodetsky et al.
Medical physics, 20(4), 1007-1012 (1993-07-01)
Noninvasive analysis of heavy elements in external tissues by diagnostic-x-ray spectrometry (DXS) is presented. Pt can be detected accurately with sensitivity below 1 microgram/g wet weight of tissue. In the present paper the possibility to monitor Pt accumulation and clearance
K R Grigorian et al.
Biofizika, 56(1), 31-34 (2011-03-30)
The interaction of cis-[PtCl2(Me2SO)2] with human serum albumin (HSA) and the sensitivity of the complex towards the thermal denaturation depending on the duration of incubation have been studied by absorption and fluorescence spectroscopy methods. Optimum conditions for cis-[PtCl2(Me2SO)2] binding to
B A Teicher et al.
Cancer chemotherapy and pharmacology, 32(4), 315-319 (1993-01-01)
The survival of bone-marrow granulocyte-macrophage colony-forming units (CFU-GM), an alkylating-agent-sensitive normal tissue, was assessed in mice bearing the EMT-6 parental tumor or the in vivo resistant EMT-6/CDDP, EMT-6/CTX, EMT-6/Thio, and EMT-6/Carbo tumors. The survival pattern of the bone-marrow CFU-GM recapitulated
Treatment of pathological stage T3N+M0 bladder cancer: the case for observation.
D A Corral et al.
Seminars in urology, 11(2), 64-68 (1993-05-01)
K Nishio et al.
International journal of cancer, 55(4), 616-622 (1993-10-21)
cis-Diamminedichloroplatinum(II) (CDDP) induced G2-phase arrest in PC-9 human cancer cells. To elucidate how CDDP acts on cell-cycle regulation, we analyzed the effect of CDDP on cell-cycle regulators such as p34cdc2 protein kinase. p34cdc2 protein kinase activity was maximum in G2
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