767654
顺-二氯双(二甲基亚砜)铂(II)
97%, solid
别名:
顺-二氯双(二甲基亚砜)铂(II), Pt(DMSO)2Cl2
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关于此项目
经验公式(希尔记法):
C4H12Cl2O2PtS2
化学文摘社编号:
分子量:
422.25
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22
产品名称
顺-二氯双(二甲基亚砜)铂(II), 97%
方案
97%
表单
solid
反应适用性
core: platinum
reagent type: catalyst
mp
218-224 °C
SMILES字符串
Cl[Pt]Cl.CS(C)=O.CS(C)=O
InChI
1S/2C2H6OS.2ClH.Pt/c2*1-4(2)3;;;/h2*1-2H3;2*1H;/q;;;;+2/p-2
InChI key
KDADQDWVKZJTDQ-UHFFFAOYSA-L
一般描述
顺式二氯双(二甲基硫亚砜)合铂(II)是一种钯复合物,可用作多种化学反应的催化剂,包括多氟芳基亚胺的甲基化和甲烷氧化。它是一种有效的C-F 活化预催化剂(precatalyst)。
应用
顺式二氯双(二甲基硫亚砜)合铂(II)可用作:
- 发烟硫酸介导的(SO3-H2SO4)甲烷氧化形成硫酸甲酯(MBS)的催化剂。
- 环金属复合物合成的前体。
警示用语:
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Enhanced catalytic activity of (DMSO) 2PtCl2 for the methane oxidation in the SO3-H2SO4 system
Dang H, et al
ACS Catalysis, 8(12), 11854-11862 (2018)
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Dietary levels of beta-carotene and vitamin E have been associated with cancer prevention and to a lesser extent, with therapeutic enhancement of cancer treatment. We report on the cytotoxicity of beta-carotene, vitamin E, and the combination of beta-carotene and vitamin
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International journal of cancer, 55(4), 616-622 (1993-10-21)
cis-Diamminedichloroplatinum(II) (CDDP) induced G2-phase arrest in PC-9 human cancer cells. To elucidate how CDDP acts on cell-cycle regulation, we analyzed the effect of CDDP on cell-cycle regulators such as p34cdc2 protein kinase. p34cdc2 protein kinase activity was maximum in G2
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D A Corral et al.
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The survival of bone-marrow granulocyte-macrophage colony-forming units (CFU-GM), an alkylating-agent-sensitive normal tissue, was assessed in mice bearing the EMT-6 parental tumor or the in vivo resistant EMT-6/CDDP, EMT-6/CTX, EMT-6/Thio, and EMT-6/Carbo tumors. The survival pattern of the bone-marrow CFU-GM recapitulated
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