792470
Me3(OMe)tBuXPhos
96% (HPLC), solid
别名:
2-Di-t-butylphosphino-4-methoxy-3,5,6-trimethyl-2′,4′,6′-tri-i-propylbiphenyl, [~1:1 mixture with regioisomer, 2-Di-t-butylphosphino-5-methoxy-3,4,6-trimethyl-2′,4′,6′-tri-i-propylbiphenyl]
产品名称
Me3(OMe)tBuXPhos, 96% (HPLC)
质量水平
方案
96% (HPLC)
表单
solid
反应适用性
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Cross Couplings
mp
125-135 °C
官能团
phosphine
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Satoshi Ueda et al.
The Journal of organic chemistry, 77(5), 2543-2547 (2012-02-09)
A new biarylphosphine ligand, Me(3)(OMe)tBuXPhos (L3), was designed as a surrogate for Me(4)tBuXPhos (L1). The Me(3)(OMe)tBuXPhos could be prepared in a chromatography-free manner from inexpensive and readily available 2,3,6-trimethylphenol. Comparative studies demonstrated that a catalyst based on Me(3)(OMe)tBuXPhos displayed the
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