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Merck
CN

794279

Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II)

solid

别名:

Buchwald Nickel Cross-Coupling Catalyst Precursor, [Bis(triphenylphosphine)](o-tolyl)chloronickel

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关于此项目

经验公式(希尔记法):
C43H37ClNiP2
化学文摘社编号:
分子量:
709.85
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
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产品名称

Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II),

form

solid

Quality Segment

reaction suitability

core: nickel, reagent type: catalyst

mp

195-200 °C

storage temp.

2-8°C

SMILES string

Cl[Ni]C1=CC=CC=C1C.P(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.P(C5=CC=CC=C5)(C6=CC=CC=C6)C7=CC=CC=C7

InChI

1S/2C18H15P.C7H7.ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;/h2*1-15H;2-5H,1H3;1H;/q;;;;+1/p-1

InChI key

QVGJKVLYWZGANE-UHFFFAOYSA-M

Application

Product is a precursor to the synthesis of an air-stable Ni-precatalyst developed by Buchwald and coworkers.


pictograms

Health hazardExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Carc. 1B - Skin Sens. 1

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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商品

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.





全球贸易项目编号

货号GTIN
794279-250MG04061833242995
794279-1G04061826655245