2,2′-Bipyrazine

Name: 2,2′-Bipyrazine
Brand: ALDRICH

97%, powder

别名:

2,2′-Bipyrazinyl, 2,2′-Dipyrazinyl

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About This Item

经验公式（希尔记法）:

C₈H₆N₄

CAS Number:

10199-00-5

分子量:

158.16

MDL编号:

MFCD00010288

UNSPSC代码:

12161600

NACRES:

NA.22

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Product Name

2,2′-Bipyrazine,

方案

97%

质量水平

100

表单

powder

反应适用性

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

mp

185-188 °C

SMILES字符串

n1c(cncc1)c2nccnc2

InChI

1S/C8H6N4/c1-3-11-7(5-9-1)8-6-10-2-4-12-8/h1-6H

InChI key

DFXNVSIALRDJHY-UHFFFAOYSA-N

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应用

2,2′-Bipyrazine (bpz) can be used as a ligand to synthesize strongly oxidizing photocatalysts. Ruthenium-based homoleptic tris(bipyrazyl) complex [(Ru(bpz)₃²⁺] derived from 2,2′-bipyrazine ligand can be used as an effective photocatalyst for oxidatively induced organic transformations. For instance, [(Ru(bpz)₃²⁺] is capable of promoting radical cation mediated Diels–Alder cycloadditions, radical thiol-ene couplings, photooxygenation reactions, and [3+2] cycloaddition reactions.