产品名称
乙醇钛,
form
liquid
Quality Level
reaction suitability
core: titanium, reagent type: catalyst
impurities
≤3% tetraisopropyl orthotitanate (NMR)
refractive index
n20/D 1.505 (lit.), n20/D 1.509
bp
150-152 °C/10 mmHg (lit.)
density
1.088 g/mL at 25 °C (lit.)
SMILES string
CCO[Ti](OCC)(OCC)OCC
InChI
1S/4C2H5O.Ti/c4*1-2-3;/h4*2H2,1H3;/q4*-1;+4
InChI key
JMXKSZRRTHPKDL-UHFFFAOYSA-N
Application
乙醇钛（IV）可用于：
- 作为活化剂和脱水剂，通过（S）-（+）-p-甲苯磺酰胺与醛和酮的缩合，形成亚磺酰亚胺。
- 作为Ti4+ 离子源形成丙烯酸钛（Ⅳ）与甲基丙烯酸的配合物。
- 作为催化剂，通过酯交换反应合成位阻醇酯。
Disclaimer
在储存期间，会形成凝胶状残余物，在加热至40℃后可溶解
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signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
107.6 °F - closed cup
flash_point_c
42 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Synthesis of sterically hindered esters via titanium catalyzed transesterification
Krasik, Pavel
Tetrahedron Letters, 39(24), 4223-4226 (1998)
Two-photon polymerization of metal ions doped acrylate monomers and oligomers for three-dimensional structure fabrication
Duan, Xuan-Ming and Sun, Hong-Bo and Kaneko, Koshiro and Kawata, Satoshi
Thin Solid Films, 453(4), 518-521 (2004)
Improved synthesis of enantiopure sulfinimines (thiooxime s-oxides) from p-toluenesulfinamide and aldehydes and ketones
Davis FA, et al.
The Journal of Organic Chemistry, 64(4), 1403-1406 (1999)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 86710-50ML | 04061833041697 |