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关于此项目
经验公式(希尔记法):
C32H52FeP2
化学文摘社编号:
分子量:
554.55
MDL number:
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352000
product line
Buchwald Ligand
assay
≥97%
form
powder
optical purity
ee: ≥99%
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Cross Couplings
functional group
phosphine
SMILES string
[Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][C]2P(C3CCCCC3)C4CCCCC4)P(C(C)(C)C)C(C)(C)C
InChI
1S/C27H47P2.C5H5.Fe/c1-21(29(26(2,3)4)27(5,6)7)24-19-14-20-25(24)28(22-15-10-8-11-16-22)23-17-12-9-13-18-23;1-2-4-5-3-1;/h14,19-23H,8-13,15-18H2,1-7H3;1-5H;/t21-;;/m1../s1
InChI key
FFFWTQLOUUWUJJ-GHVWMZMZSA-N
General description
(R)-1-[(SP)-2-(二环己基膦基)二茂铁基]乙基二-叔丁基膦(CyPF-tBu)是一种手性二茂铁基二膦配体。
与Solvias AG合作销售
Application
在钯催化的芳基溴化物/芳基三氟甲磺酸酯与硫代乙酸钾的异交叉偶联中,它可以用作配体,形成 S-芳基硫代乙酸酯。
Packaging
无底玻璃瓶。内容物在插入式融锥内。
存储类别
11 - Combustible Solids
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
A simple, base-free preparation of S-aryl thioacetates as surrogates for aryl thiols.
van den Hoogenband A, et al.
Tetrahedron Letters, 51(52), 6877-6881 (2010)
Privileged ligands
Aldrich Chemfiles, 6(8), 12-12 null
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 185760-1KG | 04061838757524 |
| 185760-250G | 04061838757531 |
| 88733-5G | 04061832627236 |
| 88733-100MG | 04061832627212 |
| 88733-1G | 04061826084496 |
| 88733-500MG | 04061832627229 |