901138
14-叠氮基3,6,9,12-四草酸酯十四烷-1-胺
别名:
2-[2-[2-[2-(2-Azidoethoxy)ethoxy]ethoxy]ethoxy]ethanamine
表单
liquid
质量水平
反应适用性
reagent type: linker
折射率
n/D 1.45
密度
1.10 g/mL
官能团
amine
azide
储存温度
2-8°C
SMILES字符串
NCCOCCOCCOCCOCCN=[N+]=[N-]
InChI
1S/C10H22N4O4/c11-1-3-15-5-7-17-9-10-18-8-6-16-4-2-13-14-12/h1-11H2
InChI key
ZMBGKXBIVYXREN-UHFFFAOYSA-N
应用
14-叠氮-3,6,9,12-四氧杂十四烷-1-胺是一种具有聚乙二醇样特征的叠氮化物，可用于通过酶微乳液聚合（enzymatic miniemulsion polymerization）和铜（I）催化点击反应制备荧光聚合物颗粒。它也可用作合成以下物质的反应物：通过N-琥珀酰亚胺基 α-芳基α-重氮基乙酸盐的氨解合成的α-芳基-α-重氮酰胺 。
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
230.0 °F
闪点(°C)
110 °C
A green approach for the synthesis of fluorescent polymer particles by combined use of enzymatic miniemulsion polymerization with clickable surfmer and click reaction
Kohri Michinari, et al.
Transactions of the Materials Research Society of Japan, 39(1), 57-60 (2014)
Joomyung V Jun et al.
Organic letters, 23(8), 3110-3114 (2021-04-06)
α-Aryl-α-diazoamides were synthesized in two steps under mild conditions. This expeditious route employs Pd-catalyzed C-H arylation of N-succinimidyl 2-diazoacetate to obtain N-succinimidyl 2-aryl-2-diazoacetates, followed by aminolysis. The ensuing diazo compounds can esterify carboxyl groups in aqueous solution, and the ester
商品
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