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Merck
CN

901409

[铱 (dF (Me) ppy)] 2 (dtbbpy) ] PF 6

solid

别名:

铱 (III) 双 [2-(2,4-二氟苯基)-5-甲基吡啶- N ,C 20 ]-4,40-二--丁基-2,20-二吡啶六氟磷酸盐

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关于此项目

经验公式(希尔记法):
C42H40F10IrN4P
化学文摘社编号:
分子量:
1013.97
MDL number:
UNSPSC Code:
12161600
NACRES:
NA.22
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产品名称

[铱 (dF (Me) ppy)] 2 (dtbbpy) ] PF 6,

form

solid

Quality Level

reaction suitability

core: iridium, reaction type: Photocatalysis, reagent type: catalyst

photocatalyst activation

450 nm

InChI key

XAJPUJWOMJJPNU-UHFFFAOYSA-N

Application

[Ir (dF (Me) ppy)] 2 (dtbbpy) ] PF 6 是一种光催化剂,容易促进烯烃的加氢胺化反应,也容易促进羧酸的脱羧芳基化反应和乙烯基化反应(通过金属卟啉催化)。

产品可与我们的光反应器系列一起使用:包括Penn PhD(Z744035)& SynLED 2.0 (Z744080


存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Victoria Dimakos et al.
Journal of the American Chemical Society, 141(13), 5149-5153 (2019-03-23)
Diphenylborinic acid serves as a cocatalyst for site- and stereoselective C-H alkylation reactions of carbohydrates under photoredox conditions using quinuclidine as the hydrogen atom transfer mediator. Products arising from selective abstraction of the equatorial hydrogens of cis-1,2-diol moieties, followed by
Correlating electronic structures to electrochemiluminescence of cationic Ir complexes.
Swanick KN, et al.
Royal Society of Chemistry Advances, 43, 19961-19964 (2013)
Adam Noble et al.
Journal of the American Chemical Society, 137(2), 624-627 (2014-12-19)
Decarboxylative cross-coupling of alkyl carboxylic acids with vinyl halides has been accomplished through the synergistic merger of photoredox and nickel catalysis. This new methodology has been successfully applied to a variety of α-oxy and α-amino acids, as well as simple



全球贸易项目编号

货号GTIN
901409-100MG04061835503476