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Merck
CN

902993

(BPhen)Ni(OAc)2.xH2O

≥95%, powder or crystals

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关于此项目

经验公式（希尔记法）:
C28H22N2NiO4
化学文摘社编号:
2304339-11-3
分子量:
509.18
MDL number:
MFCD31807324
UNSPSC Code:
12161600
NACRES:
NA.22

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产品名称

(BPhen)Ni(OAc)2.xH2O,

InChI

1S/C24H16N2.2C2H4O2.Ni/c1-3-7-17(8-4-1)19-13-15-25-23-21(19)11-12-22-20(14-16-26-24(22)23)18-9-5-2-6-10-18;2*1-2(3)4;/h1-16H;2*1H3,(H,3,4);/q;;;+2/p-2

InChI key

DONATKZVTHVGHJ-UHFFFAOYSA-L

SMILES string

O=C(O[Ni]OC(C)=O)C.C1(C2=CC=CC=C2)=CC=NC3=C1C=CC4=C3N=CC=C4C5=CC=CC=C5

assay

≥95%

form

powder or crystals

reaction suitability

core: nickel
reaction type: Cross Couplings
reagent type: catalyst

mp

>300 °C

相关类别

Application

Catalyst for cross couplings via C-N bond activation

Disclaimer

Store under N2 atmosphere

Other Notes

Harnessing Alkyl Amines as Electrophiles for Nickel-Catalyzed Cross Couplings via C–N Bond Activation

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Corey H Basch et al.
Journal of the American Chemical Society, 139(15), 5313-5316 (2017-04-01)
We developed a strategy to harness alkyl amines as alkylating agents via C-N bond activation. This Suzuki-Miyaura cross coupling of alkylpyridinium salts, readily formed from primary amines, is the first example of a metal-catalyzed cross coupling via C-N bond activation

商品

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

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