903000
[4,4′-双（1,1-二甲基乙基）-2,2′-联吡啶]二氯化镍（II）
powder or crystals
别名:
(4,4′-dtbbpy)NiCl2
产品名称
[4,4′-双（1,1-二甲基乙基）-2,2′-联吡啶]二氯化镍（II）,
表单
powder or crystals
反应适用性
core: nickel
reaction type: Cross Couplings
reagent type: catalyst
mp
>300 °C
SMILES字符串
CC(C1=CC(C2=CC(C(C)(C)C)=CC=N2)=NC=C1)(C)C.Cl[Ni]Cl
InChI key
PCWIKFRTCXESOT-UHFFFAOYSA-L
应用
[4,4′-双(1,1-二甲基乙基)-2,2′-联吡啶]二氯化镍(II)作为催化剂已用于：
- 含氧酸的脱羧芳基化。
- 醚的酰化。
- 芳基溴和醇的交叉偶联反应。
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Merging photoredox and nickel catalysis: The direct synthesis of ketones by the decarboxylative arylation of α-oxo acids
Chu L, et al.
Angewandte Chemie (International ed. in English), 127, 8040-8044 (2015)
Martins S Oderinde et al.
The Journal of organic chemistry, 80(15), 7642-7651 (2015-07-04)
In order to achieve reproducibility during iridium-photoredox and nickel dual-catalyzed sp(3)-sp(2) carbon-carbon bond-forming reactions, we investigated the role that molecular oxygen (O2), solvent and light-source (CF lamp or blue LED) play in a variety of Ir-photoredox mediated transformations. The presence
Ir III/Ni II-Metallaphotoredox catalysis: the oxidation state modulation mechanism versus the radical mechanism
Zhu B, et al.
Chemical Communications (Cambridge, England), 54, 5968-5971 (2018)
Photocatalytic α-Acylation of Ethers
Sun Z, et al.
Organic Letters, 19, 3727-3730 (2017)
Aryl Ketones as Single-Electron-Transfer Photoredox Catalysts in Nickel-Catalyzed the Homocoupling of Aryl Halides
Masuda Y, et al.
European Journal of Organic Chemistry, 5822-5825 (2016)
商品
Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.
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