903000
[4,4′-双（1,1-二甲基乙基）-2,2′-联吡啶]二氯化镍（II）
powder or crystals
别名:
(4,4′-dtbbpy)NiCl2
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关于此项目
经验公式（希尔记法）:
C18H24Cl2N2Ni
化学文摘社编号:
分子量:
398.00
MDL number:
UNSPSC Code:
12352101
NACRES:
NA.22
产品名称
[4,4′-双（1,1-二甲基乙基）-2,2′-联吡啶]二氯化镍（II）,
form
powder or crystals
reaction suitability
core: nickel, reaction type: Cross Couplings, reagent type: catalyst
mp
>300 °C
SMILES string
CC(C1=CC(C2=CC(C(C)(C)C)=CC=N2)=NC=C1)(C)C.Cl[Ni]Cl
InChI key
PCWIKFRTCXESOT-UHFFFAOYSA-L
Application
[4,4′-双(1,1-二甲基乙基)-2,2′-联吡啶]二氯化镍(II)作为催化剂已用于：
- 含氧酸的脱羧芳基化。
- 醚的酰化。
- 芳基溴和醇的交叉偶联反应。
Other Notes
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
商品
Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.
Ir III/Ni II-Metallaphotoredox catalysis: the oxidation state modulation mechanism versus the radical mechanism
Zhu B, et al.
Chemical Communications (Cambridge, England), 54, 5968-5971 (2018)
Aryl Ketones as Single-Electron-Transfer Photoredox Catalysts in Nickel-Catalyzed the Homocoupling of Aryl Halides
Masuda Y, et al.
European Journal of Organic Chemistry, 5822-5825 (2016)
Photocatalytic α-Acylation of Ethers
Sun Z, et al.
Organic Letters, 19, 3727-3730 (2017)