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Merck
CN

905518

Ir(dFFppy)2(dtbbpy)PF6

solid

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关于此项目

经验公式（希尔记法）:
C40H34F12IrN4P
化学文摘社编号:
2042201-18-1
分子量:
1021.90
MDL number:
MFCD31807347
UNSPSC Code:
12161600
NACRES:
NA.22

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产品名称

Ir(dFFppy)2(dtbbpy)PF6,

SMILES string

FC1=C(C2=NC=C(F)C=C2)C([Ir]3([N]4=CC=C(C(C)(C)C)C=C4C5=CC(C(C)(C)C)=CC=[N]53)C6=CC(F)=CC(F)=C6C7=CC=C(F)C=N7)=CC(F)=C1.FP(F)(F)(F)(F)F

form

solid

reaction suitability

core: iridium
reagent type: catalyst
reaction type: Photocatalysis

mp

>300 °C

photocatalyst activation

465 nm

相关类别

Application

Ir(dFFppy)2(dtbbpy)PF6 is a versatile photocatalyst that can be used for a variety of synthetic transformations.
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Metallaphotoredox-catalysed sp3–sp3cross-coupling of carboxylic acids with alkyl halides

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCS1997

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Craig P Johnston et al.
Nature, 536(7616), 322-325 (2016-08-19)
In the past 50 years, cross-coupling reactions mediated by transition metals have changed the way in which complex organic molecules are synthesized. The predictable and chemoselective nature of these transformations has led to their widespread adoption across many areas of

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