905925
[Pd(terpy)(2-Cl-phen)](BF4)2
≥95%, powder or crystals
别名:
Ritter fluorination catalyst
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关于此项目
经验公式（希尔记法）:
C27H18B2ClF8N5Pd
化学文摘社编号:
分子量:
727.95
MDL number:
UNSPSC Code:
12161600
NACRES:
NA.22
产品名称
[Pd(terpy)(2-Cl-phen)](BF4)2 , ≥95%
SMILES string
ClC(C=C1)=NC2=C1C=CC3=CC=C[N]([Pd]45[N]6=C(C7=CC=CC=[N]75)C=CC=C6C8=CC=CC=[N]84)=C32
assay
≥95%
form
powder or crystals
reaction suitability
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
mp
>300 °C
storage temp.
2-8°C
Application
[Pd(terpy)(2-Cl-phen)](BF4)2 was developed in the Ritter lab for the elecrophilic fluorination of arenes.
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Legal Information
This product is manufactured pursuant to a license with Studiengesellschaft Kohle mbH (US Patent Pending 16/083,160 and PCT/US2017/021563).
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
新产品
此项目有
Kumiko Yamamoto et al.
Nature, 554(7693), 511-514 (2018-02-23)
Aryl fluorides are widely used in the pharmaceutical and agrochemical industries, and recent advances have enabled their synthesis through the conversion of various functional groups. However, there is a lack of general methods for direct aromatic carbon-hydrogen (C-H) fluorination. Conventional
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