907111
2,6-bis(N-pyrazolyl)pyridine nickel(II) bromide
powder or crystals
别名:
(bpp)NiBr2
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关于此项目
经验公式（希尔记法）:
C11H9Br2N5Ni
化学文摘社编号:
分子量:
429.72
MDL number:
UNSPSC Code:
12352101
NACRES:
NA.22
产品名称
2,6-bis(N-pyrazolyl)pyridine nickel(II) bromide,
SMILES string
[Ni+].[Br-].Br.[n]3(nccc3)c1nc(ccc1)[n]2nccc2
InChI key
ZVPBBPDZLUQKSN-UHFFFAOYSA-M
InChI
1S/C11H9N5.2BrH.Ni/c1-4-10(15-8-2-6-12-15)14-11(5-1)16-9-3-7-13-16;;;/h1-9H;2*1H;/q;;;+1/p-1
form
powder or crystals
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
mp
>300 °C
Application
Precatalyst for alkyl-alkyl cross-coupling; reductive cross-coupling of styrenyl aziridines, dialkyl ether formation, reductive amination.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
新产品
此项目有
Christoph Heinz et al.
Journal of the American Chemical Society, 140(6), 2292-2300 (2018-01-18)
This report describes a three-component, Ni-catalyzed reductive coupling that enables the convergent synthesis of tertiary benzhydryl amines, which are challenging to access by traditional reductive amination methodologies. The reaction makes use of iminium ions generated in situ from the condensation
相关内容
Doyle group focuses on nucleophilic fluorination using PyFluor and nickel catalysis with modular, air-stable nickel precatalyst.
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