908886
N-Cyano-4-methoxy-picolinimidamide
≥95%, powder or crystals
别名:
Weix ligand
产品名称
N-Cyano-4-methoxy-picolinimidamide, ≥95%
方案
≥95%
表单
powder or crystals
反应适用性
reagent type: catalyst
reaction type: Cross Couplings
mp
220-225 °C
SMILES字符串
N(C(=N)c1nccc(c1)OC)C#N
InChI
1S/C8H8N4O/c1-13-6-2-3-11-7(4-6)8(10)12-5-9/h2-4H,1H3,(H2,10,12)
InChI key
LEWHOCRDELQPCV-UHFFFAOYSA-N
应用
This pyridyl carboxamidine ligand has been demonstrated by Daniel Weix′s lab to enable nickel-catalyzed cross-coupling of diverse basic nitrogen heterocycles with primary and secondary alkyl halides.
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Eric C Hansen et al.
Nature chemistry, 8(12), 1126-1130 (2016-11-23)
Ligands are essential for controlling the reactivity and selectivity of reactions catalysed by transition metals. Access to large phosphine ligand libraries has become an essential tool for the application of metal-catalysed reactions industrially, but these existing libraries are not well
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