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经验公式(希尔记法):
C12H12Cl2N2NiO2
化学文摘社编号:
分子量:
345.84
MDL number:
NACRES:
NA.23
UNSPSC Code:
12161600
产品名称
(4,4′-dMeObpy)NiCl2,
form
powder or crystals
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
mp
>300 °C
Application
(4,4′-dMeObpy)NiCl2 is a Ni catalyst used for a variety of cross-coupling reactions.
Other Notes
signalword
Danger
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 Inhalation - Muta. 2 - Repr. 2 - STOT RE 1 Inhalation
target_organs
Respiratory Tract
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Zhongdong Sun et al.
Organic letters, 19(14), 3727-3730 (2017-07-12)
Direct coupling of ethers and acyl halides was promoted by a binary catalytic system comprising an Ir-based photocatalyst and a Ni complex under blue-light irradiation. Photocatalysts with high triplet energy directed the catalysis, and the reaction likely proceeded by triplet-triplet
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