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Merck
CN

911607

[Ir(dFOMeppy)2-(5,5′-dCF3bpy)]PF6

≥95%, powder or crystals

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关于此项目

经验公式（希尔记法）:
C36H22F16IrN4O2P
化学文摘社编号:
2307271-69-6
分子量:
1069.75
MDL number:
MFCD32672288
UNSPSC Code:
12161600
NACRES:
NA.22

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产品名称

[Ir(dFOMeppy)2-(5,5′-dCF3bpy)]PF6 , ≥95%

SMILES string

[Ir+](c5c(c(cc(c5)F)F)c6ncc(cc6)OC)c3c(c(cc(c3)F)F)c4ncc(cc4)OC.FC(F)(F)c1cnc(cc1)c2ncc(cc2)C(F)(F)F.F[P-](F)(F)(F)(F)F

InChI

1S/C12H6F6N2.2C12H8F2NO.F6P.Ir/c13-11(14,15)7-1-3-9(19-5-7)10-4-2-8(6-20-10)12(16,17)18;2*1-16-9-3-5-12(15-7-9)10-4-2-8(13)6-11(10)14;1-7(2,3,4,5)6;/h1-6H;2*2-3,5-7H,1H3;;/q;;;-1;+1

InChI key

VCHHFLJLUYSBMX-UHFFFAOYSA-N

assay

≥95%

form

powder or crystals

reaction suitability

reaction type: Photocatalysis
reagent type: catalyst

mp

>300 °C

photocatalyst activation

465 nm

相关类别

Application

[Ir(dFOMeppy)2-(5,5′-dCF3bpy)]PF6 is a versatile photocatalyst that can be used for a variety of synthetic transformations including the trifluoromethylation of alkyl bromides.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Copper-Catalyzed Trifluoromethylation of Alkyl Bromides

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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David J P Kornfilt et al.
Journal of the American Chemical Society, 141(17), 6853-6858 (2019-04-16)
Copper oxidative addition into organohalides is a challenging two-electron process. In contrast, formal oxidative addition of copper to Csp2 carbon-bromine bonds can be accomplished by employing latent silyl radicals under photoredox conditions. This novel paradigm for copper oxidative addition has

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