912794
Ni(COD)(DQ)
≥95%, powder
别名:
Bis(1,5-cyclooctadiene)(duroquinone) nickel(0)
登录 查看组织和合同定价。
选择规格
变更视图
关于此项目
经验公式（希尔记法）:
C18H24NiO2
化学文摘社编号:
分子量:
331.08
MDL number:
UNSPSC Code:
12352103
NACRES:
NA.22
产品名称
Ni(COD)(DQ), ≥95%
Quality Segment
assay
≥95%
form
powder
reaction suitability
reagent type: catalyst
core: nickel
reaction type: Cross Couplings
parameter
temperature stable
mp
227 °C (decomposition)
SMILES string
[Ni](C)C.O=C2C(=C(C(=O)C(=C2C)C)C)C.C1CCC\C=C/CC1
InChI key
PRUJUYLPWIUASG-ZMKTYRQVSA-N
Application
Ni(COD)(DQ), as shown by the Engle lab, is an air- and thermally stable Ni(0) precatalyst. This 18-electron complex has a unique stability profile allowing for easy reaction setup outside an inert atmosphere. Transformations such as the Suzuki-Miyaura coupling, borylation of aryl halides, and alkene hydroarylation have been demonstrated.
signalword
Danger
hcodes
Hazard Classifications
Carc. 2 - Skin Sens. 1 - STOT RE 1
target_organs
Lungs
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
flash_point_f
Not applicable
flash_point_c
Not applicable