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Merck
CN

912948

Ir[FCF3(CF3)ppy]2(dtbbpy)PF6

powder

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关于此项目

经验公式（希尔记法）:
C44H34F20IrN4P
化学文摘社编号:
2222402-20-0
分子量:
1221.93
MDL number:
MFCD32851671
UNSPSC Code:
12352101
NACRES:
NA.22

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产品名称

Ir[FCF3(CF3)ppy]2(dtbbpy)PF6,

InChI key

HNVAXJZTSVKZHB-UHFFFAOYSA-N

SMILES string

[Ir+].FC(F)(F)c5cnc(cc5)c6c(cc(cc6)C(F)(F)F)F.FC(F)(F)c3cnc(cc3)c4c(cc(cc4)C(F)(F)F)F.F[P-](F)(F)(F)(F)F.n1c(cc(cc1)C(C)(C)C)c2nccc(c2)C(C)(C)C

form

powder

reaction suitability

reaction type: Photocatalysis
reagent type: catalyst

mp

378 °C

Quality Level

100

相关类别

Application

Ir[FCF3(CF3)ppy]2(dtbbpy)PF6 is a versatile photocatalyst that can be used for a variety of synthetic transformations including the α-arylation of alcohols.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Selective Hydrogen Atom Abstraction through Induced Bond Polarization: Direct α-Arylation of Alcohols through Photoredox, HAT, and Nickel Catalysis

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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分析证书(COA)

Lot/Batch Number
MKCV1240
MKCM1271

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Jack Twilton et al.
Angewandte Chemie (International ed. in English), 57(19), 5369-5373 (2018-03-01)
The combination of nickel metallaphotoredox catalysis, hydrogen atom transfer catalysis, and a Lewis acid activation mode, has led to the development of an arylation method for the selective functionalization of alcohol α-hydroxy C-H bonds. This approach employs zinc-mediated alcohol deprotonation

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