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Merck
CN

913154

1,10-Phenanthroline nickel (ll) dibromide

powder

别名:

(phen)NiBr2

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关于此项目

经验公式（希尔记法）:
C12H8Br2N2Ni
化学文摘社编号:
48165-50-0
分子量:
398.71
MDL number:
MFCD32851677
UNSPSC Code:
12352200
NACRES:
NA.22

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产品名称

1,10-Phenanthroline nickel (ll) dibromide,

SMILES string

Br[Ni]1(Br)[N]2=CC=CC3=C2C([N]1=CC=C4)=C4C=C3

form

powder

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

Quality Level

100

相关类别

Application

1,10-Phenanthroline nickel (ll) dibromide is a Ni precatalyst used for a variety of cross-coupling reactions, including N-alkylation of amides and arylation of alcohols.

Other Notes

Selective Hydrogen Atom Abstraction through Induced Bond Polarization: Direct α-Arylation of Alcohols through Photoredox, HAT, and Nickel Catalysis

存储类别

11 - Combustible Solids

wgk

WGK 3

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Jack Twilton et al.
Angewandte Chemie (International ed. in English), 57(19), 5369-5373 (2018-03-01)
The combination of nickel metallaphotoredox catalysis, hydrogen atom transfer catalysis, and a Lewis acid activation mode, has led to the development of an arylation method for the selective functionalization of alcohol α-hydroxy C-H bonds. This approach employs zinc-mediated alcohol deprotonation

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