918970
VincePhos
≥95%, powder
别名:
7,7,9,9-Tetramethyl-8-(2′,4′,6′-triisopropyl-3,6-dimethoxy-[1,1′-biphenyl]-2-yl)-1,4-dioxa-8-phosphaspiro[4.5]decane
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选择尺寸
关于此项目
经验公式（希尔记法）:
C34H51O4P
化学文摘社编号:
分子量:
554.74
MDL number:
UNSPSC Code:
12352112
NACRES:
NA.22
产品名称
VincePhos, ≥95%
SMILES string
P3(C(CC4(OCCO4)CC3(C)C)(C)C)c1c(ccc(c1c2c(cc(cc2C(C)C)C(C)C)C(C)C)OC)OC
InChI
1S/C34H51O4P/c1-21(2)24-17-25(22(3)4)29(26(18-24)23(5)6)30-27(35-11)13-14-28(36-12)31(30)39-32(7,8)19-34(20-33(39,9)10)37-15-16-38-34/h13-14,17-18,21-23H,15-16,19-20H2,1-12H3
InChI key
BYFHGEFWDTYSSA-UHFFFAOYSA-N
assay
≥95%
form
powder
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings, reagent type: ligand
functional group
phosphine
storage temp.
−20°C
Quality Level
Application
VincePhos is a biaryl phosphorinane ligand for Pd catalysis. This ligand has been used in a variety of Pd-catalyzed reactions including the sulfonamidation of aryl halides, C-O couplings, and C-N couplings.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
David M Barnes et al.
The Journal of organic chemistry, 84(8), 4873-4892 (2019-01-11)
Dasabuvir (1) is an HCV polymerase inhibitor which has been developed as a part of a three-component direct-acting antiviral combination therapy. During the course of the development of the synthetic route, two novel coupling reactions were developed. First, the copper-catalyzed
Pd-Catalyzed Cross-Coupling Reactions Promoted by Biaryl Phosphorinane Ligands.
Laffoon S D, et al.
ACS Catalysis, 9(12), 11691-11708 (2019)
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