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Merck
CN

919365

(MeBPI)Ni-OAc

powder

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经验公式（希尔记法）:
C22H19N5NiO2
分子量:
444.11
UNSPSC Code:
12352200
NACRES:
NA.22
Form:
powder

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产品名称

(MeBPI)Ni-OAc,

form

powder

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

mp

>300 °C

Quality Level

100

相关类别

Application

(MeBPI)Ni-OAc is a Ni catalyst developed in the Sevov lab for electrocatalytic cross-electrophile coupling reactions. When combined with a redox-active shuttle (918105), (MeBPI)Ni-OAc enables the reductive coupling of a wide range of aryl, heteroaryl, or vinyl bromides with primary or secondary alkyl bromides.

Product can be used with our Synlectro electrochemistry platform (ESYNTH001)

Other Notes

General C(sp2)-C(sp3) Cross-Electrophile Coupling Reactions Enabled by Overcharge Protection of Homogeneous Electrocatalysts

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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Blaise L Truesdell et al.
Journal of the American Chemical Society, 142(12), 5884-5893 (2020-03-03)
Cross-electrophile coupling (XEC) of alkyl and aryl halides promoted by electrochemistry represents an attractive alternative to conventional methods that require stoichiometric quantities of high-energy reductants. Most importantly, electroreduction can readily exceed the reducing potentials of chemical reductants to activate catalysts

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