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Merck
CN

923486

(CyMPhos)PdCl2

greener alternative

powder, complex with CH₂Cl₂

别名:

1-Diadamantylphosphino-1′-dicyclohexylphosphinoferrocene palladium dichloride

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关于此项目

经验公式(希尔记法):
C42H60Cl2FeP2Pd
化学文摘社编号:
分子量:
860.04
MDL number:
NACRES:
NA.21
UNSPSC Code:
12352101
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产品名称

(CyMPhos)PdCl2, complex with CH2Cl2

Quality Level

form

powder

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

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Greener Alternative Product

greener alternative category

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

(CyMPhos)PdCl2 is an unsymmetrical ferrocene-based Pd-catalyst. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. (CyMPhos)PdCl2 can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp2-Csp3 coupling. Demonstrated Csp2-Csp3 couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR2)).

Learn more about MPhos ligands and catalysts


pictograms

Health hazardExclamation mark

signalword

Warning

Hazard Classifications

Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp2?Csp3 Couplings
Xu, et al.
ACS Catalysis, 12, 5123?5135-5123?5135 (2022)



全球贸易项目编号

货号GTIN
923486-100MG04065267062532
923486-500MG04065267062549