923486
(CyMPhos)PdCl2
powder, complex with CH₂Cl₂
别名:
1-Diadamantylphosphino-1′-dicyclohexylphosphinoferrocene palladium dichloride
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关于此项目
经验公式（希尔记法）:
C42H60Cl2FeP2Pd
化学文摘社编号:
分子量:
860.04
MDL number:
NACRES:
NA.21
UNSPSC Code:
12352101
产品名称
(CyMPhos)PdCl2, complex with CH2Cl2
form
powder
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
greener alternative product characteristics
Catalysis
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General description
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Application
(CyMPhos)PdCl2 is an unsymmetrical ferrocene-based Pd-catalyst. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. (CyMPhos)PdCl2 can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp2-Csp3 coupling. Demonstrated Csp2-Csp3 couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR2)).
Learn more about MPhos ligands and catalysts
Learn more about MPhos ligands and catalysts
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Warning
hcodes
Hazard Classifications
Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp2?Csp3 Couplings
Xu, et al.
ACS Catalysis, 12, 5123?5135-5123?5135 (2022)
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