925209
RuCl(p-异丙基甲苯)[(S,S)-Ts-DPEN]
Umicore, powder
别名:
[N-[(1S,2S)-2-(氨基-κN)-1,2-二苯基乙基]-4-甲基苯磺酰胺合-κN]氯[(1,2,3,4,5,6-η)-1-甲基-4-(1-甲基乙基)苯]-钌
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关于此项目
经验公式（希尔记法）:
C31H35ClN2O2RuS
化学文摘社编号:
分子量:
636.21
NACRES:
NA.22
UNSPSC Code:
12352116
MDL number:
产品名称
RuCl(p-异丙基甲苯)[(S,S)-Ts-DPEN], Umicore
InChI key
AZFNGPAYDKGCRB-XCPIVNJJSA-M
SMILES string
CC(C)c1ccc(C)cc1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@H]([C@@H](N)c3ccccc3)c4ccccc4
InChI
1S/C21H21N2O2S.C10H14.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-8(2)10-6-4-9(3)5-7-10;;/h2-15,20-21H,22H2,1H3;4-8H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m0.../s1
form
powder
mp
>175 °C
storage temp.
2-8°C
Quality Level
Application
催化剂涉及：
手性氨基酰胺烷基配合物热分解研究中的反应物
- 亚胺和酮的不对称转移加氢
- 分子内不对称还原胺化
- 末端烯烃的串联氢甲酰化/氢化
手性氨基酰胺烷基配合物热分解研究中的反应物
RuCl(p-cymene)[(S,S)-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium, which can be used for the asymmetric transfer hydrogenation of a variety of imines.
Preparation Note
Do not store above 25 °C (77 °F). Store in a tightly closed original container under dry inert gas, protected from direct sunlight in a dry, cool and well-ventilated area.
Legal Information
Product of Umicore
This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.
Additional information available at www.pmc.umicore.com
This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.
Additional information available at www.pmc.umicore.com
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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