926116
(R,R)-Ts-DENEB™
powder
别名:
stereoisomer of Chloro[4-methyl-N-[(1R,2R)-2-[(S)-[2-[[(1,2,3,4,5,6-η)-4-methylphenyl]methoxy]ethyl]amino-κN]-1,2-diphenylethyl]benzenesulfonamidato-κN]ruthenium
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关于此项目
经验公式（希尔记法）:
C31H33ClN2O3RuS
化学文摘社编号:
分子量:
650.19
MDL number:
UNSPSC Code:
12161600
NACRES:
NA.22
产品名称
(R,R)-Ts-DENEB™,
functional group
phosphine
Quality Level
InChI key
INKUCOHLIHBSDN-ZAMYOOMVSA-M
SMILES string
[Ru+2].[S](=O)(=O)([N-][C@@H]([C@H](NCCOCc4ccc(cc4)C)c3ccccc3)c2ccccc2)c1ccc(cc1)C.[Cl-]
form
powder
reaction suitability
reagent type: ligand
Application
(R,R)-Ts-DENEB™ is an oxo-tethered ruthenium complex for use as an efficient asymmetric hydrogenation catalyst.
Legal Information
Product of Takasago.
For research and development purposes only. PCT/JP2011/064490
For research and development purposes only. PCT/JP2011/064490
DENEB is a trademark of Takasago Intl. Corp.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
新产品
此项目有
Taichiro Touge et al.
Journal of the American Chemical Society, 133(38), 14960-14963 (2011-08-30)
Newly developed oxo-tethered Ru amido complexes (R,R)-1 and their HCl adducts (R,R)-2 exhibited excellent catalytic performance for both asymmetric transfer hydrogenation and the hydrogenation of ketonic substrates under neutral conditions without any cocatalysts to give chiral secondary alcohols with high
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