92748
对硝基苯基三甲基硅乙基碳酸酯
≥97.0%, for peptide synthesis
别名:
2-(三甲基硅基)乙基 4-硝基苯基碳酸酯, TEOC-ONp
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关于此项目
经验公式（希尔记法）:
C12H17NO5Si
化学文摘社编号:
分子量:
283.35
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352108
EC Number:
279-406-7
MDL number:
Beilstein/REAXYS Number:
4320585
产品名称
对硝基苯基三甲基硅乙基碳酸酯, ≥97.0%
Quality Segment
assay
≥97.0%
form
crystals
mp
35-40 °C
application(s)
peptide synthesis
functional group
carbonate, nitro
storage temp.
2-8°C
SMILES string
C[Si](C)(C)CCOC(=O)Oc1ccc(cc1)[N+]([O-])=O
InChI
1S/C12H17NO5Si/c1-19(2,3)9-8-17-12(14)18-11-6-4-10(5-7-11)13(15)16/h4-7H,8-9H2,1-3H3
InChI key
ZAQWGGKIMQIVGM-UHFFFAOYSA-N
Application
4-Nitrophenyl 2-(trimethylsilyl)ethyl carbonate can be used as:
- A protecting group for an amine in one of the key synthetic steps of kottamide E total synthesis.
- A starting material to prepare a cis-butene derivative, which is used as a polymer terminating agent in the synthesis of monotelechelic glycopolymers.
Other Notes
用于引入 TEOC-氨基保护基团的试剂，TEOC-氨基保护基团可被 F- 裂解
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)