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Merck
CN

938734

Sigma-Aldrich

EPhos Pd G6 Br

greener alternative

powder

别名:

(EPhos)Pd(p-CF3C6H4)(Br)

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关于此项目

经验公式（希尔记法）:
C43H59BrF3OPPd
分子量:
866.22
NACRES:
NA.21

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产品名称

EPhos Pd G6 Br,

表单

powder

质量水平

100

反应适用性

core: palladium
reaction type: Cross Couplings
reagent type: catalyst

环保替代产品特性

Catalysis
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sustainability

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颜色

faint yellow

官能团

phosphine

环保替代产品分类

Aligned

SMILES字符串

CC(C)OC1=CC=CC(C2=C(C(C)C)C=C(C(C)C)C=C2C(C)C)=C1[P]([Pd](Br)C3=CC=C(C(F)(F)F)C=C3)(C4CCCCC4)C5CCCCC5

InChI

InChI=1S/C36H55OP.C7H4F3.BrH.Pd/c1-24(2)28-22-32(25(3)4)35(33(23-28)26(5)6)31-20-15-21-34(37-27(7)8)36(31)38(29-16-11-9-12-17-29)30-18-13-10-14-19-30;8-7(9,10)6-4-2-1-3-5-6;;/h15,20-27,29-30H,9-14,16-19H2,1-8H3;2-5H;1H;

InChI key

BUVPEGXQNXKJOG-UHFFFAOYSA-N

相关类别

一般描述

(EPhos Pd G6 Br) is a G6 Buchwald precatalyst. The G6 precatalysts are air-stable, palladium-based oxidative addition complexes (OACs) that offer an alternative to the previously developed classes of palladacycle precatalysts. Unlike previous generations, the bulkiest biarylphosphine ligand precatalysts are readily prepared. These precatalysts have been shown to be effective for many reactions, including C-N, C-O, and C-F cross couplings.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

应用

The Buchwald G6 precatalysts are oxidative addition complexes (OACs), which exhibit the same advantages as the previous generations of Buchwald precatalysts: quantitative generation of L–Pd(0), thermal stability, air stability, moisture stability, ease of handling, and high efficiency.

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCV9281

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商品

Buchwald G6 Precatalysts: Oxidative Addition Complexes

Buchwald G6 precatalysts are oxidative addition complexes that are thermally, air, and moisture stable. The catalyst activation doesn’t require a base and generates innocuous byproducts.

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