B91005
肼基甲酸叔丁酯
98%, for peptide synthesis
别名:
Boc-肼, 叔丁氧羰基肼
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关于此项目
线性分子式:
(CH3)3COCONHNH2
化学文摘社编号:
分子量:
132.16
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352108
EC Number:
212-795-3
MDL number:
Beilstein/REAXYS Number:
1756967
产品名称
肼基甲酸叔丁酯, 98%
InChI key
DKACXUFSLUYRFU-UHFFFAOYSA-N
InChI
1S/C5H12N2O2/c1-5(2,3)9-4(8)7-6/h6H2,1-3H3,(H,7,8)
SMILES string
O=C(NN)OC(C)(C)C
assay
98%
form
crystals
bp
63-65 °C/0.1 mmHg (lit.)
mp
39-42 °C (lit.)
application(s)
peptide synthesis
Quality Level
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Application
用于与乙烯基卤化物进行钯催化交叉偶联反应，生成 N-叔丁氧羰基-N-烯基肼。
用于固相多肽合成和 α-氨基醛的光学纯度测定的试剂。可与醛发生缩合反应形成腙，腙可作为合成 HIV-1 蛋白酶抑制剂的中间体。
用于固相多肽合成和 α-氨基醛的光学纯度测定的试剂。可与醛发生缩合反应形成腙，腙可作为合成 HIV-1 蛋白酶抑制剂的中间体。
Tetrahedron Letters, 34, 5425-5425 (1993)
Tetrahedron Letters, 34, 6599-6599 (1993)
Journal of the Chemical Society. Chemical Communications, 1052-1052 (1993)
José Barluenga et al.
Organic letters, 9(2), 275-278 (2007-01-16)
N-Boc-N-alkenylhydrazines, an almost unknown type of compounds, have been prepared with high to moderate yields via palladium-catalyzed cross-coupling between alkenyl halides and tert-butyl carbazate. The present methodology represents the first general way to access this highly functionalized and unusual type
Martina Bruna Violatto et al.
ACS nano, 13(4), 4410-4423 (2019-03-19)
Steroids are the standard therapy for autoimmune hepatitis (AIH) but the long-lasting administration is hampered by severe side effects. Methods to improve the tropism of the drug toward the liver are therefore required. Among them, conjugation to nanoparticles represents one
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