蒸汽压
0.03 mmHg ( 40 °C)
质量水平
方案
98%
反应适用性
core: iron
reagent type: catalyst
沸点
249 °C (lit.)
mp
172-174 °C (lit.)
λmax
358 nm
储存温度
2-8°C
SMILES字符串
[Fe].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2
InChI
1S/2C5H5.Fe/c2*1-2-4-5-3-1;/h2*1-5H;
InChI key
DFRHTHSZMBROSH-UHFFFAOYSA-N
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应用
二茂铁(二环戊二烯基铁)可用于:
- 用作不对称催化中的手性配体支架。
- 染料敏化太阳能电池应用中的二茂铁基电解质。
- 合成不对称二茂铁配体,可用作交叉偶联、氢化、烯丙基取代的催化剂。
- 通过化学气相沉积法合成二维六方有序介孔碳(CMK-5),用作甲醇氧化的催化剂载体。
- 合成二茂铁与富勒烯的分子杂化物(巴基二茂铁)。
- 制备二茂铁盐,用作温和氧化剂。
警示用语:
Danger
危险分类
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 1 - Flam. Sol. 1 - Repr. 1B - STOT RE 2 Inhalation
靶器官
Liver
储存分类代码
4.1B - Flammable solid hazardous materials
WGK
WGK 2
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
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